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Deschanels, X.; Broudic, V.; Jegou, C.; Peuget, S.; Roudil, D.; Jorion, F.; Advocat, T.
Commissariat a l'Energie Atomique (CEA), Valrho/Marcoule, BP 17171, 30207 Bagnols-sur-Ceze Cedex (France)2004
Commissariat a l'Energie Atomique (CEA), Valrho/Marcoule, BP 17171, 30207 Bagnols-sur-Ceze Cedex (France)2004
AbstractAbstract
[en] Zirconolite is a potential matrix for the immobilization of the minor actinides stream produced by the reprocessing of the spent fuel. In order to check the incorporation of actinide into the structure, zirconolite ceramic pellets doped with 10 wt% in 239PuO2 were sintered. Characterization by SEM, XRD and XANES spectroscopy have been done on this material. The microstructural homogeneity of the pellets is good, and their relative density is higher than 90% of the theoretical density. XANES spectroscopy shows that Pu is at the oxidation state IV in this material. To investigate the effects of radiation damage on zirconolite structure, pellets doped with 10 wt% of 238PuO2 were fabricated. The 238Pu accelerates the radiation damage relative to the 239Pu because of its much higher specific activity (63.2 x 1010 Bq/g for 238Pu vs. 2.2 x 109 Bq/g for 238Pu). Some pellets are storing at ambient, 250 deg. C and 500 deg C. Up 1019 α/cm3, the macroscopic swelling of the samples stored at ambient is about 0.5% by 1018 α/cm3, and the microscopic one near 0.35% by 1018 α/cm3. Some microcracks are observed on these pellets. The samples started to become amorphous at 1019 α/cm3. The swelling strongly decreases with the storage temperature of the samples. The leaching rate of 239Pu doped ceramics measured by Soxhlet tests at 100 deg. C in deionized water appears to be the same as inactive material. (authors)
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2004; 6 p; 2. ATALANTE 2004 conference: Advances for future nuclear fuel cycles; Nimes (France); 21-24 Jun 2004; 13 refs., 8 figs., 4 tabs.
Record Type
Report
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Conference
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ACTINIDE NUCLEI, ACTINIDES, ALPHA DECAY RADIOISOTOPES, CHARGED PARTICLES, COHERENT SCATTERING, DIFFRACTION, ELEMENTS, EVEN-EVEN NUCLEI, EVEN-ODD NUCLEI, HEAVY ION DECAY RADIOISOTOPES, HEAVY NUCLEI, IONIZING RADIATIONS, ISOTOPES, MATERIALS, METALS, MINERALS, NUCLEI, OXIDE MINERALS, PLUTONIUM ISOTOPES, RADIATIONS, RADIOISOTOPES, SCATTERING, SEPARATION PROCESSES, SILICON 32 DECAY RADIOISOTOPES, SPONTANEOUS FISSION RADIOISOTOPES, TEMPERATURE RANGE, TRANSURANIUM ELEMENTS, YEARS LIVING RADIOISOTOPES
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