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AbstractAbstract
[en] The design and development of sorption-active natural and synthetic polymer fibers and textile materials is of great scientific and practical interest. The advantages of that type of polymeric adsorbents, as their highly developed specific surface, excellent ion-exchange and adsorption parameters and ease of their use especially under continuous conditions, allow them to find a great application in the chemical, biomedical, ecological and industrial fields. To obtain functional polymer materials with the desired performance, the non-active polymer surface have to be modified. Among different innovative techniques used for the introduction of graft chains, the radiation-chemical method of initiation has some economical and ecological preferences over others. It allows to introduce into inert polymeric matrix chains of a monomer already containing a desirable functional group, or to graft chains of a precursor-monomer and subsequently its chemical modification to form required functional groups. At present an epoxy-group containing monomer, glycidyl methacrylate (GMA), is successfully used as a precursor-monomer for production of polymeric adsorbents of variety applications on the base of membranes, films, fibers and fabrics. Two types of sorption-active polypropylene fiber carrying strong-acid sulfonate groups and amino groups have been synthesized by radiation-induced graft polymerization of GMA, with subsequent chemical modification of the epoxy groups of poly-GMA graft chains. The effect of various polymerization parameters on the GMA grafting degree was investigated in detail. The epoxy ring-opening of poly-GMA graft chains with introduction of strong-acid sulfonate groups was carried out with sodium hydrogen sulfite in water-dimethylformamide solution at 70 deg C. The main peculiarities of the sulfonation reaction in depending on the reaction time and GMA grafting degree have been investigated. Amine groups were incorporated by treatment of the GMA-grafted polypropylene fibers with excess of diethylene triamine reagent. The conversion of the epoxy groups into the functional groups was investigated as a function of the degree of GMA grafting and reaction time. The ion-exchange characteristics of obtained sorption-active polypropylene fibers have been determined. Keywords: Nonwoven polypropylene fibers, synthesis, electron beam irradiation, functionalization of polymers, graft copolymerization. (author)
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Yuldashev, B.; Fazylov, M.; Ibragimova, E.; Salikhbaev, U. (eds.); Uzbekistan Academy of Sciences, Institute of Nuclear Physics, Tashkent (Uzbekistan). Funding organisation: The Abdus Salam International Center for Theoretical Physics, Trieste (Italy); Science and Technology Center in Ukraine, Kiev (Ukraine); CHEMOTRADE GmbH Co. KG, Duesseldorf (Germany); Lawrence Livermore National Laboratory, University of California (United States); Zimmermann BCS Stones LTD, Harxheim, (Germany); Navoi Mining and Metallurgical Complex, Navoi (Uzbekistan); 'Radiopreparat' Enterprise, Tashkent (Uzbekistan); Physical Technical Institute, Science Association 'Physics-Sun', Uzbekistan Academy of Sciences, Tashkent (Uzbekistan); Joint Venture 'Tezintom', Tashkent (Uzbekistan); 'Tezlatgich' Enterprise, Tashkent (Uzbekistan); Almalyk Mining and Metallurgical Complex, Almalyk (Uzbekistan); 390 p; Sep 2006; p. 325-326; 6. International conference on modern problems of nuclear physics; Tashkent (Uzbekistan); 19-22 Sep 2006
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