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AbstractAbstract
[en] The subject of this thesis is the investigation of the thermal transport properties of three classes of transition-metal oxides: Cuprates, cobaltates, and manganites. The layered cuprates R2CuO4 with R=La, Pr, Nd, Sm, Eu, and Gd show an anomalous thermal conductivity κ. Two maxima of κ are observed as a function of temperature for a heat current within the CuO2 planes, whereas for a heat current perpendicular to the CuO2 planes only a conventional phononic low-temperature maximum of κ is present. Evidence is provided that the high-temperature maximum is caused by heat-carrying excitations on the CuO2 square lattice. Moreover, it is shown that the complex low-temperature and magnetic-field behavior of κ in Nd2CuO4 is most likely caused by additional phonon scattering rather than by heat-carrying Nd magnons, as it was proposed in the literature. In the cobaltates RCoO3 with R=La, Pr, Nd, and Eu, a temperature-induced spin-state transition of the Co3+ ions occurs. It is shown that the additional lattice disorder caused by the random distribution of populated higher spin states causes a large suppression of the thermal conductivity of LaCoO3 for T>25 K. The effect is much weaker in PrCoO3 and NdCoO3 due to the increased spin gap. A quantitative analysis of the responsible mechanisms based on EuCoO3 as a reference compound is provided. A main result is that the static disorder is sufficient to explain the suppression of κ. No dynamical Jahn-Teller distortion, as proposed in the literature, is necessary to enhance the scattering strength. Below 25 K, k is mainly determined by resonant phonon scattering on paramagnetic impurity levels, e.g. caused by oxygen non-stoichiometry. Such a suppression of the thermal conductivity by resonant scattering processes is e.g. known from Holmium ethylsulfate. This effect is most pronounced in LaCoO3, presumably due to magnetic polaron formation. In the doped compounds La1-xSrxCoO3 with 0≤x≤0.25, a large thermopower, a low thermal conductivity, and a considerable large thermoelectric figure of merit is found. Here, κ is strongly suppressed by the Sr-induced magnetic polarons, whereas the large thermopower arises from a large entropy contribution due to the different spin states of Co3+ and Co4+. In the orthorhombic manganites NdMnO3 and TbMnO3 complex temperature and field dependencies of κ are observed. In combination with magnetic-field dependent thermal expansion measurements it is shown that the dominating effect determining κ is resonant phonon scattering by the 4f orbitals of the R3+ ions. The complicated magnetic structure of TbMnO3 at low temperature as well as the ferroelectricity has only a minor influence on the thermal conductivity. (orig.)
Primary Subject
Source
Sep 2006; 207 p; Diss.
Record Type
Miscellaneous
Literature Type
Thesis/Dissertation; Numerical Data
Report Number
Country of publication
COBALT IONS, COBALT OXIDES, CUPRATES, EUROPIUM OXIDES, EXPERIMENTAL DATA, GADOLINIUM COMPOUNDS, LANTHANUM OXIDES, LAYERS, MAGNETIC FIELDS, MAGNETIC SUSCEPTIBILITY, MANGANESE OXIDES, NEODYMIUM OXIDES, ORTHORHOMBIC LATTICES, PHONONS, PRASEODYMIUM OXIDES, RESONANCE SCATTERING, SAMARIUM COMPOUNDS, SPIN ORIENTATION, STRONTIUM OXIDES, TEMPERATURE DEPENDENCE, TEMPERATURE RANGE 0000-0013 K, TEMPERATURE RANGE 0013-0065 K, TEMPERATURE RANGE 0065-0273 K, TEMPERATURE RANGE 0273-0400 K, TERBIUM OXIDES, THERMAL CONDUCTIVITY, THERMAL EXPANSION, THERMOELECTRIC PROPERTIES
ALKALINE EARTH METAL COMPOUNDS, CHALCOGENIDES, CHARGED PARTICLES, COBALT COMPOUNDS, COPPER COMPOUNDS, CRYSTAL LATTICES, CRYSTAL STRUCTURE, DATA, ELECTRICAL PROPERTIES, EUROPIUM COMPOUNDS, EXPANSION, INELASTIC SCATTERING, INFORMATION, IONS, LANTHANUM COMPOUNDS, MAGNETIC PROPERTIES, MANGANESE COMPOUNDS, NEODYMIUM COMPOUNDS, NUMERICAL DATA, ORIENTATION, OXIDES, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, PRASEODYMIUM COMPOUNDS, QUASI PARTICLES, RARE EARTH COMPOUNDS, SCATTERING, STRONTIUM COMPOUNDS, TEMPERATURE RANGE, TERBIUM COMPOUNDS, THERMODYNAMIC PROPERTIES, TRANSITION ELEMENT COMPOUNDS
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