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AbstractAbstract
[en] Back-side contact Au and Ag microelectrodes were used as transducers to construct planar all-solid-state electrodes suitable for flow-through analysis. The microsensors were based on plasticized PVC potassium-selective membranes containing ion-electron conducting polymer-polypyrrole doped with di(2-ethylhexyl) sulfosuccinate. The proposed technique allowed simple construction of microsensors in one step, by membrane solution casting directly on the surface of the planar metallic transducers. The performance of the microsensors based on Au and Ag transducers were determined and compared with planar sensors based on internal electrolyte immobilized in polyHEMA. The addition of the polypyrrole to the membrane composition did not influence on the selectivity, reproducibility and long-term stability of the microsensors but improved their standard potential stability in time in comparison with coated-wire type sensors. Moreover, all-solid-state microsensors based on Au transducers exhibited better signal stability than Ag based sensors
Primary Subject
Source
International symposium 'Analytical Forum 2004'; Warsaw (Poland); 4-8 Jul 2004; S0003-2670(04)01154-7; Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Literature Type
Conference
Journal
Country of publication
AZOLES, CARBOXYLIC ACIDS, CHEMICAL ANALYSIS, CHLORINATED ALIPHATIC HYDROCARBONS, DICARBOXYLIC ACIDS, ELECTRICAL PROPERTIES, ELECTRODES, HALOGENATED ALIPHATIC HYDROCARBONS, HETEROCYCLIC COMPOUNDS, MATERIALS, ORGANIC ACIDS, ORGANIC CHLORINE COMPOUNDS, ORGANIC COMPOUNDS, ORGANIC HALOGEN COMPOUNDS, ORGANIC NITROGEN COMPOUNDS, ORGANIC POLYMERS, PHYSICAL PROPERTIES, POLYMERS, POLYVINYLS, QUANTITATIVE CHEMICAL ANALYSIS, TITRATION, VOLUMETRIC ANALYSIS
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