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AbstractAbstract
[en] Studying of migration forms of heave metals (HM) in the river waters was conducted by the following scheme: Neutron-activation analysis of divided fractions of separate forms of HM; experimental modeling by using of appropriate radio nuclides and thermodynamic modeling methods. There was developed and used neutron-activation method for getting quantitative data about forms of being HM in water. The ultra-filtration and electrodialyze fractionating and concentrating of separate forms of HM was carried out before neutron activation analyses. There were established optimal conditions of division form of being of HM by using radionuclides Co 60, Cr 51 and Sb 124 in cationic and anionic forms. During 2003-2005 we have studied space-temporarily variations of content and phase distribution of Hg, Zn, Cd, Sb, Co, Th, Br, Cr, Au, La and Eu in the waters of Amudarya, Syrdarya and Surkhandarya rivers. Average concentration of HM fluctuates from 4,1 mg/l for Fe, till 2 ng/l for Au. Suspended composing of river waters makes from mountain rock and lands in river-heads and concentration of elements in weight form not exceeding the level of Clark's contents. In formation of solved phase of river water main role plays atmospheric precipitation. This fact concern to the technogenic elements (Hg, Cd, Zn, Sb, Cr, Se, V) mainly. Limits of determination of HM - 10-6-10-10g/l. Relative mis-take of definition of 20 HM, including Hg, Zn, Cd, Sb, Co, U, Br and Cr in the river and sewage waters makes 10-25 %. It was established that researching elements in river waters migrates in suspended, colloid, cationic, anionic and neutral forms. Contents of colloid form of HM fluctuate between 5 % and 20 %. A comparable low content of organic matters in river waters of arid zones stipulates perceptivity of applying of thermodynamic methods in studying of being forms of HM. The thermodynamic calculations for determination being forms of HM in river waters were also carried out. On the base of experimental data and thermodynamic modeling, it was established that in distinction of river waters of humid zones, in migrations of HM in surface water in arid zones main role plays inorganic ligands (OH-, SO42-, Cl-). Received results about forms of being HM and radionuclides may be the base for developing the technology of water preparation on water-pipe stations of researched rivers, and for effective clearing water from HM and radionuclides. In this work the contents of the different forms of heavy metals in the rivers of Uzbekistan were analyzed. The thermodynamic calculations for determination of being forms of heavy metals in river waters were carried out. Received results about forms of being HM and radionuclides can be the base for developing the technology of water preparation on water-pipe stations of researched rivers, and for effective clearing water from HM and radionuclides. (authors)
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Kundas, S.P.; Mel'nov, S.B.; Poznyak, S.S. (International A. Sakharov environmental univ., Minsk (Belarus)) (eds.); Ministehrstva adukatsyi Rehspubliki Belarus', Minsk (Belarus); Ministehrstva pryrodnykh rehsursaw i akhovy navakol'naga asyaroddzya Rehspubliki Belarus', Minsk (Belarus); Kamiteht pa prablemam nastupstvaw katastrofy na Charnobyl'skaj AEhS pry Savetse Ministraw Rehspubliki Belarus', Minsk (Belarus); Belaruski rehspublikanski fond fundamental'nykh dasledvannyaw, Minsk (Belarus); Tsentral'no-evropejskaya initsiativa, Minsk (Belarus); International A. Sakharov environmental univ., Minsk (Belarus); 304 p; ISBN 978-985-6823-33-9;
; May 2007; p. 188; 7. international scientific conference 'Sakharov readings 2007: Ecological problems of XXI century'; 7. Mezhdunarodnaya nauchnaya konferentsiya 'Sakharovskie chteniya 2007 goda: Ekologicheskie problemy XXI veka'; Minsk (Belarus); 17-18 May 2007

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Miscellaneous
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Conference
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ACTIVATION ANALYSIS, ANTIMONY ISOTOPES, ASIA, BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, CHEMICAL ANALYSIS, CHROMATOGRAPHY, CHROMIUM ISOTOPES, COBALT ISOTOPES, DAYS LIVING RADIOISOTOPES, DIALYSIS, ELECTRON CAPTURE RADIOISOTOPES, ELEMENTS, ENVIRONMENTAL TRANSPORT, EVEN-ODD NUCLEI, FILTRATION, INTERMEDIATE MASS NUCLEI, INTERNAL CONVERSION RADIOISOTOPES, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, MASS TRANSFER, METALS, MINUTES LIVING RADIOISOTOPES, NONDESTRUCTIVE ANALYSIS, NUCLEI, ODD-ODD NUCLEI, POLLUTION, RADIOISOTOPES, SEPARATION PROCESSES, SURFACE WATERS, YEARS LIVING RADIOISOTOPES
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