Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.014 seconds
AbstractAbstract
[en] Among perovskite manganites, a series La1-x Ca x MnO3 has the largest magnetocaloric effect (MCE) (|ΔS m|max=3.2-6.7 J/kg K in ΔH=1.35 T) but their Curie temperatures, T C, are quite low (165-270 K). A system La1-x Pb x MnO3 has quite high T C (235-360 K) but exhibits not so large MCE (0.65-1.53 J/kg K). The manganites La0.7Ca0.3-x Pb x MnO3 (x=0.05, 0.10, 0.15, and 0.20) have been fabricated by solid-state reaction technique with the expectation that they could establish large MCE at room temperature region. The prepared samples are of single phase with orthorhombic structure. Lattice parameters as well as volume of unit cell are continuously increased with increasing x due to large Pb2+ ions substituted for smaller Ca2+ ions. There is spin-glass (or cluster glass)-like state occurring in studied samples. T C increases continuously from 270 K (for x=0.05) to 338 K (for x=0.20). Large MCE has been obtained in all samples and vertical bar ΔS m vertical barmax reached the highest value of 3.72 J/kg K (with magnetic field variation ΔH=1.35 T) for the sample x=0.05 and the studied samples could be considered as giant magnetocaloric materials working for magnetic refrigeration. The magnetoresistance of samples exhibited colossal value
Primary Subject
Source
17. international conference on magnetism; Kyoto (Japan); 20-25 Aug 2006; S0304-8853(06)02290-6; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Literature Type
Conference
Journal
Journal of Magnetism and Magnetic Materials; ISSN 0304-8853;
; CODEN JMMMDC; v. 310(2); p. 2826-2828

Country of publication
CALCIUM COMPOUNDS, CALCIUM IONS, CURIE POINT, LANTHANUM COMPOUNDS, LATTICE PARAMETERS, LEAD COMPOUNDS, LEAD IONS, MAGNETIC FIELDS, MAGNETIC PROPERTIES, MAGNETIC REFRIGERATORS, MAGNETORESISTANCE, MANGANESE COMPOUNDS, ORTHORHOMBIC LATTICES, OXIDES, PEROVSKITE, REFRIGERATION, SPIN GLASS STATE, TEMPERATURE RANGE 0273-0400 K
ALKALINE EARTH METAL COMPOUNDS, CHALCOGENIDES, CHARGED PARTICLES, COOLING, CRYSTAL LATTICES, CRYSTAL STRUCTURE, ELECTRIC CONDUCTIVITY, ELECTRICAL PROPERTIES, IONS, MINERALS, OXIDE MINERALS, OXYGEN COMPOUNDS, PEROVSKITES, PHYSICAL PROPERTIES, RARE EARTH COMPOUNDS, REFRIGERATORS, TEMPERATURE RANGE, THERMODYNAMIC PROPERTIES, TRANSITION ELEMENT COMPOUNDS, TRANSITION TEMPERATURE
Publication YearPublication Year
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue