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Qu Hongbo; Li Haiyang; Liang Feng; Zhang Bing, E-mail: bzhang@wipm.ac.cn2006
AbstractAbstract
[en] The photodissociation of n-C7H15Br, near the red wing of the absorption A-band, has been investigated utilizing the velocity mapped ion imaging technique. Both the speed and angular distributions of Br*(2P1/2) and Br(2P3/2) fragments were determined. The experimental data indicate that the photodissociation in the investigated range originates from adiabatic and non-adiabatic transitions of the three low-lying dissociative electronic states. The fragments kinetic energies and the angular distributions show that about 70% energy is deposited into the internal energy of the fragments. These results can be explained using soft impulsive model. The experiment also shows that the anisotropy parameter for Br* is sensitive to the photolysis wavelength
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S0301-0104(06)00490-3; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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