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AbstractAbstract
[en] The microstructure, crystal structure, and magnetotransport properties of microsized and nanosized Badoped manganites have been investigated. A 'two-step' reduction-reoxidation procedure has been used to obtain nanosized ceramic manganite Nd0.70Ba0.30MnO3 (II). The parent microsized manganite Nd0.70Ba0.30MnO3 (I) was prepared by usual ceramic technology in air. Then the sample was annealed in vacuum. The grain size of the reduced sample, determined by scanning electron microscopy, decreased from ∼5 μm down to ∼100 nm. To obtain the oxygen stoichiometry nanosized sample, the Nd0.70Ba0.30MnO2.60 was again annealed in air. It is established that the (I) sample is a pseudocubic perovskite, whereas (II) is tetrahedral as a consequence of Nd3+ and Ba2+ ions as well as the ordering of oxygen vacancies. The (I) sample is a ferromagnet with TC ∼ 140 K. It has metal-insulator transition at TMI ∼ 135 K and a peak of magnetoresistance ∼50% in a field of 9 kOe. For the (II) sample, the critical points of phase transitions move to higher temperatures, TC ∼ 320 K and TMI ∼ 310 K. The magnetoresistance of the (II) sample at room temperature (T ∼ 293 K) is about 7% in a field of 9 kOe. The magnetotransport properties are interpreted in the framework of the nanosized effect
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Copyright (c) 2007 Nauka/Interperiodica; Article Copyright (c) 2007 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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ANNEALING, BARIUM COMPOUNDS, BARIUM IONS, CERAMICS, DOPED MATERIALS, GRAIN SIZE, MAGNETORESISTANCE, MANGANESE COMPOUNDS, NANOSTRUCTURES, NEODYMIUM COMPOUNDS, NEODYMIUM IONS, OXIDES, PEROVSKITE, PHASE TRANSFORMATIONS, SCANNING ELECTRON MICROSCOPY, TEMPERATURE RANGE 0065-0273 K, TEMPERATURE RANGE 0273-0400 K, VACANCIES
ALKALINE EARTH METAL COMPOUNDS, CHALCOGENIDES, CHARGED PARTICLES, CRYSTAL DEFECTS, CRYSTAL STRUCTURE, ELECTRIC CONDUCTIVITY, ELECTRICAL PROPERTIES, ELECTRON MICROSCOPY, HEAT TREATMENTS, IONS, MATERIALS, MICROSCOPY, MICROSTRUCTURE, MINERALS, OXIDE MINERALS, OXYGEN COMPOUNDS, PEROVSKITES, PHYSICAL PROPERTIES, POINT DEFECTS, RARE EARTH COMPOUNDS, SIZE, TEMPERATURE RANGE, TRANSITION ELEMENT COMPOUNDS
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