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AbstractAbstract
[en] The Japan Atomic Energy Agency (JAEA) has been conducting R and D on hydrogen production by the thermochemical Iodine-Sulfur (IS) process to meet the massive hydrogen demand in the future hydrogen economy. In the IS process, sulfuric acid (H2SO4) is evaporated and decomposed into H2O and SO3 in a H2SO4 decomposer operated under high-temperature condition up to 500degC. We have proposed a new decomposer concept of a block-type heat exchanger made of SiC ceramic, which has a salient corrosion-resistant performance under severe corrosion condition. To verify the mechanical feasibility of the concept, the temperature distributions of sulfuric acid and helium gas were analyzed using a newly coded analytical system applicable to binary mixtures such as H2SO4 whose boiling point depends on the concentration. Thermomechanical simulations with a general-purpose FEM code, which used the heat exchange simulation results, showed that the maximum stress was generated around the dryout region, which was about half of the allowable tensile stress of SiC. (author)
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Available in fulltext at URL: http://wwwsoc.nii.ac.jp/aesj/publication/TAESJ2008/No.2/7_2_134-141.pdf; Copyright (c) 2008 Atomic Energy Society of Japan, Tokyo, Japan, All rights reserved; 20 refs., 7 figs., 3 tabs.
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Journal Article
Journal
Nippon Genshiryoku Gakkai Wabun Ronbunshi; ISSN 1347-2879;
; v. 7(2); p. 134-141

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CARBIDES, CARBON COMPOUNDS, CHEMICAL REACTIONS, COMPUTER CODES, ELEMENTS, ENRICHED URANIUM REACTORS, EXPERIMENTAL REACTORS, GAS COOLED REACTORS, GRAPHITE MODERATED REACTORS, HALOGENS, HELIUM COOLED REACTORS, HTGR TYPE REACTORS, HYDROGEN COMPOUNDS, INORGANIC ACIDS, INORGANIC COMPOUNDS, KINETICS, NONMETALS, OXYGEN COMPOUNDS, REACTION KINETICS, REACTORS, RESEARCH AND TEST REACTORS, SILICON COMPOUNDS, SIMULATION, STRESSES, SULFUR COMPOUNDS
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