[en] Positron annihilation lifetime spectroscopy was used to observe the effects of argon intercalation in some solid long-chain alkanes at high pressure. The ortho-Ps lifetime rises with argon pressure, which means increase of free volumes in the alkane structure. The range of pressures in which the rotator phase exists increases, comparing to pure alkane. In n-heptadecane, n-nonadecane, and possibly n-heneicosane, a stepwise change of ortho-Ps lifetime and intensity at ∼12 MPa is observed, suggesting the transition to a new kind of the rotator phase. The transition rate is low, final lifetime value is ∼3.3 ns. Despite a large size of free volumes corresponding to such a lifetime, their compressibility is found negligible up to the pressure of 90 MPa. At low pressures the compressibility of free volumes in the rotator phase is negative