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[en] Stoichiometric sodium bis(dihydrotellurato)cuprate(III) of the composition Na5[Cu(H2TeO6)2] . 16H2O is synthesized, and its crystal structure is studied. The site occupancy of the Na(3) atom at the center of symmetry is refined to 0.493(8). Since this value is close to 0.5, the position is considered to be completely occupied
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