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AbstractAbstract
[en] In the processing of carbon/carbon composites using polymer resin as the matrix precursor, it is inevitable that a porous structure was formed after carbonization. As a result, densification by liquid phase impregnation followed by recarbonization is required to obtain a densified composite. Consequently, the char formability of resin is an important factor in reducing the number of densification cycles and hence the processing cost. In this study, a novel approach is adopted to improve the densification of carbon/carbon composites by using a new phenolic resin modified by pitch. For this purpose, soluble part of pitch was extracted and dispersed in resol type phenolic resin. The polymerization reaction was performed in presence of para-formaldehyde and a resol-pitch compound was obtained. The second compound was prepared by mixing novolac-furfural in 55:45 weight ratio containing 9% by weight hexamethylene tetramine. This compound was added to resol-pitch compound in 10,20,50 and 80 w %. The microstructure of carbonized resin was investigated by X-ray diffraction and char yield, and the linear and volumetric shrinkage were obtained. Results show that in 80:20 ratio of resol-pitch to novolac-furfural , the char yield would be maximized by 71% and volumetric shrinkage would be minimized at 16.4%. At the same time, XRD results indicate that the resin has a strong ability to graphitize carbon/carbon composites matrix as a necessary step for its processing
Original Title
Behbood-e carbon dehi-e zarin phenoli be manzoor-e estefade dar sakht-e composit-haye carbon-carbon
Primary Subject
Source
Available from Atomic Energy Organization of Iran
Record Type
Journal Article
Journal
Polymer Science and Technology; ISSN 1016-3255;
; v. 21(no.2); p. 127-132

Country of publication
ALDEHYDES, AROMATICS, CHEMICAL REACTIONS, COHERENT SCATTERING, DECOMPOSITION, DIFFRACTION, ELEMENTS, FURANS, HETEROCYCLIC COMPOUNDS, HYDROXY COMPOUNDS, MATERIALS, NONMETALS, ORGANIC COMPOUNDS, ORGANIC OXYGEN COMPOUNDS, ORGANIC POLYMERS, OTHER ORGANIC COMPOUNDS, PETROCHEMICALS, PETROLEUM PRODUCTS, PHENOLS, POLYMERS, SCATTERING
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