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Deokate, R.J.; Pawar, S.M.; Moholkar, A.V.; Sawant, V.S.; Pawar, C.A.; Bhosale, C.H.; Rajpure, K.Y., E-mail: kyr_phy@unishivaji.ac.in2008
AbstractAbstract
[en] The cadmium oxide (CdO) and F:CdO films have been deposited by spray pyrolysis method using cadmium acetate and ammonium fluoride as precursors for Cd and F ions, respectively. The effect of temperature and F doping on the structural, morphological, optical and Hall effect properties of sprayed CdO thin films was investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), optical absorption and electrical measurement techniques. TGA and DTA studies, indicates the formation of CdO by decomposition of cadmium acetate after 250 deg. C. XRD patterns reveal that samples are polycrystalline with cubic structure and exhibits (2 0 0) preferential orientation. Considerable broading of (2 0 0) peak, simultaneous shifting of corresponding Bragg's angle have been observed with respect to F doping level. SEM and AFM show the heterogeneous distribution of cubical grains all over the substrate, which are randomly distributed. F doping shifts the optical gap along with the increase in the transparency of CdO films. The Hall effect measurement indicates that the resistivity and mobility decrease up to 4% F doping
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S0169-4332(07)01279-2; Available from http://dx.doi.org/10.1016/j.apsusc.2007.09.006; Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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CADMIUM COMPOUNDS, CHALCOGENIDES, CHEMICAL ANALYSIS, CHEMICAL REACTIONS, COHERENT SCATTERING, DECOMPOSITION, DIFFRACTION, ELECTRON MICROSCOPY, ELEMENTS, FILMS, GRAVIMETRIC ANALYSIS, HALOGENS, MATERIALS, MICROSCOPY, NONMETALS, OPTICAL PROPERTIES, OXIDES, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, QUANTITATIVE CHEMICAL ANALYSIS, SCATTERING, SORPTION, THERMAL ANALYSIS, THERMOCHEMICAL PROCESSES
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