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Tetu, Amelie; Chevallier, Jacques; Nielsen, Brian Bech, E-mail: atetu@phys.au.dk2008
AbstractAbstract
[en] In this work we demonstrate that InSb nanocrystals embedded in SiO2 display a substantial melting-point hysteresis. Transmission electron microscopy was performed after heat treatment on the 500 nm-thick SiO2 films doped with 10 at.% of In and Sb atoms in order to verify the presence of the nanocrystals, identify their crystalline form, and obtain their size distribution. The crystalline zinc-blende structure of the InSb nanocrystals was further confirmed with X-ray diffraction characterization. The planar distances and the cubic structure were derived from the X-ray diffraction spectrum. Furthermore, it showed that the nanocrystals have a planar distance slightly smaller than for the bulk crystals, indicating that the nanocrystals are exposed to a compressive stress which we estimate to be 14 kbar. Both superheating and supercooling of the nanocrystals could be observed by following the diffraction pattern of the nanocrystals using TEM. The melting-point hysteresis was measured to be about 19% of the melting temperature of bulk InSb
Primary Subject
Source
E-MRS 2007: Symposium B on Semiconductor nanostructures towards electronic and optoelectronic device applications; Strasbourg (France); 28 May - 1 Jun 2007; S0921-5107(07)00440-0; Available from http://dx.doi.org/10.1016/j.mseb.2007.08.004; Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Literature Type
Conference
Journal
Materials Science and Engineering. B, Solid-State Materials for Advanced Technology; ISSN 0921-5107;
; CODEN MSBTEK; v. 147(2-3); p. 141-143

Country of publication
ANTIMONIDES, ANTIMONY COMPOUNDS, CHALCOGENIDES, COHERENT SCATTERING, DIFFRACTION, ELECTRON MICROSCOPY, FILMS, HEATING, INDIUM COMPOUNDS, INORGANIC PHOSPHORS, MATERIALS, MICROSCOPY, MINERALS, OXIDE MINERALS, OXIDES, OXYGEN COMPOUNDS, PHASE TRANSFORMATIONS, PHOSPHORS, PHYSICAL PROPERTIES, PNICTIDES, SCATTERING, SILICON COMPOUNDS, SULFIDES, SULFUR COMPOUNDS, THERMODYNAMIC PROPERTIES, TRANSITION TEMPERATURE, ZINC COMPOUNDS
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