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[en] A theoretical full-relaxation matrix analysis of heteronuclear Overhauser effects in oligosaccharides is described. This analysis predicts that trans-glycosidic heteronuclear 1H{13C} NOEs should be measurable in a model disaccharide with appropriate enrichment with 13C and 2H. These predictions are confirmed experimentally, and the value of these measurements is discussed for conformational analysis
Journal
Journal of Biomolecular NMR; ISSN 0925-2738; 
; v. 11(3); p. 289-294
; v. 11(3); p. 289-294