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Barahona, P.; Pena, O.; Antunes, A.B.; Campos, C.; Pecchi, G.; Moreno, Y.; Moure, C.; Gil, V., E-mail: pbaraho@ucm.cl2008
AbstractAbstract
[en] Partial substitution of manganese by cobalt in rare-earth perovskites REMnO3 leads to unusual magnetic phenomena because of the simultaneous presence of Mn3+, Mn4+, Co2+ and Co3+ species. The magnetic nature of the RE cation plays a fundamental role in the magnetic properties. We present herein two specific families: for RE=La the magnetic behavior of the |Co+Mn| network is observed, while for Gd its strong magnetic moment interacts with the transition metals, leading to a spin reversal state. Magnetic interactions are maximized at x=0.50, as if two regimes exist: for x<0.5 Co substitutes Mn in the REMnO3 manganite, and for x>0.5 Mn substitutes Co in the RECoO3 cobaltite
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8. Latin American workshop on magnetism, magnetic materials and their applications; Rio de Janeiro (Brazil); 12-16 Aug 2007; S0304-8853(08)00087-5; Available from http://dx.doi.org/10.1016/j.jmmm.2008.02.017; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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