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AbstractAbstract
[en] Polymer gels are crosslinked polymer networks swollen by a fluid. If magnetic particles either as powder or dispersed in a magnetic fluid are introduced into the gel then the system becomes sensitive to external magnetic fields and the resulting material is called ferrogel. The polyvinyl alcohol (PVA)-magnetite ferrogels system has properties that are attractive for artificial muscles and drug delivery systems for biomedical applications. This work investigates the synthesis and characterization of a ferrogel obtained by freezing-thawing cycles. PVA (MW=89,000-98,000, degree of hydrolyzation: 99 mol%) and magnetite nanoparticles (∼12 nm) obtained by chemical coprecipitation were used as raw materials. The PVA-magnetite ferrogels were prepared by subjecting a PVA/DMSO/magnetite solution (2 g/30 ml/0.2 g) to freeze (-25 deg. C)/thaw (+25 deg. C) cycles. The resulting ferrogel was characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), differential scanning calorimetry (DSC) and vibration sample magnetometry (VSM). The magnetic particles inside the PVA matrix formed agglomerates with average size ∼58 nm. All the ferrogels showed superparamagnetic behavior with maximum magnetization of 0.6 emu/g
Primary Subject
Source
8. Latin American workshop on magnetism, magnetic materials and their applications; Rio de Janeiro (Brazil); 12-16 Aug 2007; S0304-8853(08)00185-6; Available from http://dx.doi.org/10.1016/j.jmmm.2008.02.073; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Literature Type
Conference
Journal
Journal of Magnetism and Magnetic Materials; ISSN 0304-8853;
; CODEN JMMMDC; v. 320(14); p. e373-e376

Country of publication
ALCOHOLS, CHEMICAL REACTIONS, COHERENT SCATTERING, COLLOIDS, DIFFRACTION, DISPERSIONS, ELECTRON MICROSCOPY, EMISSION, HYDROXY COMPOUNDS, IRON ORES, MAGNETISM, MAGNETOMETERS, MATERIALS, MEASURING INSTRUMENTS, MICROSCOPY, MINERALS, ORES, ORGANIC COMPOUNDS, ORGANIC POLYMERS, ORGANIC SULFUR COMPOUNDS, OXIDE MINERALS, PHASE TRANSFORMATIONS, POLYMERIZATION, POLYMERS, POLYVINYLS, PRECIPITATION, SCATTERING, SEPARATION PROCESSES, SULFOXIDES
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