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Markina, M.; Vasilchikova, T.; Vasiliev, A.; Lemmens, P.; Valldor, M., E-mail: markina@lt.phys.msu.ru2008
AbstractAbstract
[en] The magnetic susceptibility and specific heat measurements were performed on YBaCo4-xZnxO7 in a wide temperature range. This compound is characterized by a mixed valence of Co (Co2+/Co3+) and has a kagome-like layered magnetic arrangement of spin moments in the P63mc hexagonal crystal structure. This arrangement is known for strong frustration of magnetic interactions and prevents the formation of long range magnetically ordered ground states. However, peak-like anomalies were found in the magnetic susceptibility at the temperatures 66, 27, 15 and 3 K for x=0, 1, 2, 3, respectively. Small anomalies in the specific heat at the related temperatures were found for x=1, 2, 3, indicating the magnetic freezing of the spin system. Zn-substitution changes the ratio Co2+/Co3+ which strongly influences the magnitudes and temperatures of anomalies in magnetic susceptibility and specific heat. The increase of Zn content in YBaCo4-xZnxO7 leads to a rapid decrease of the magnetic contribution in the specific heat in a wide temperature range
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Source
8. Latin American workshop on magnetism, magnetic materials and their applications; Rio de Janeiro (Brazil); 12-16 Aug 2007; S0304-8853(08)00203-5; Available from http://dx.doi.org/10.1016/j.jmmm.2008.02.080; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Literature Type
Conference
Journal
Journal of Magnetism and Magnetic Materials; ISSN 0304-8853;
; CODEN JMMMDC; v. 320(14); p. e434-e436

Country of publication
ALKALINE EARTH METAL COMPOUNDS, ANGULAR MOMENTUM, CHALCOGENIDES, CHARGED PARTICLES, CRYSTAL LATTICES, CRYSTAL STRUCTURE, ENERGY LEVELS, EQUIPMENT, IONS, MAGNETIC PROPERTIES, OXYGEN COMPOUNDS, PARTICLE PROPERTIES, PHASE TRANSFORMATIONS, PHYSICAL PROPERTIES, TEMPERATURE RANGE, THERMODYNAMIC PROPERTIES, TRANSITION ELEMENT COMPOUNDS
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