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Wang Zhongzhu; Bi Hong; Liu Jian; Sun Tao; Wu Xianliang, E-mail: wangzz@ahu.edu.cn2008
AbstractAbstract
[en] The conducting protonated polyaniline (ES)/γ-Fe2O3 nanocomposite with the different γ-Fe2O3 content were synthesized by in-situ polymerization. Its morphology, microstructure, DC conductivity and magnetic properties of samples were characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), four-wire-technique, and vibrating sample magnetometer (VSM), respectively. The microwave absorbing properties of the nanocomposite powders dispersing in wax coating with the coating thickness of 2 mm were investigated using a vector network analyzers in the frequency range of 7-18 GHz. The pure ES has shown the absorption band with a maximum absorption at approximately 16 GHz and a width (defined as frequency difference between points where the absorption is more than 8 dB) of 3.24 GHz, when 10% γ-Fe2O3 by weight is incorporated , the width is broadened to 4.13 GHz and some other absorption bands appear in the range of 7-13 GHz. The parameter dielectric loss tan δe (=ε''/ε') in the 7-18 GHz is found to decrease with increasing γ-Fe2O3 contents with 10%, 20%, 30%, respectively, but magnetic loss tan δm (=μ''/μ') increases with increasing γ-Fe2O3 contents. The results show that moderate content of γ-Fe2O3 nanoparticles embedded in protonated polyaniline matrix may create advanced microwave absorption properties due to simultaneous adjusting of dielectric loss and magnetic loss
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Source
S0304-8853(08)00346-6; Available from http://dx.doi.org/10.1016/j.jmmm.2008.03.043; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Journal
Journal of Magnetism and Magnetic Materials; ISSN 0304-8853;
; CODEN JMMMDC; v. 320(16); p. 2132-2139

Country of publication
AMINES, AROMATICS, CHALCOGENIDES, CHEMICAL REACTIONS, ELECTRICAL PROPERTIES, ELECTROMAGNETIC RADIATION, ELECTRON MICROSCOPY, FREQUENCY RANGE, GHZ RANGE, IRON COMPOUNDS, MAGNETOMETERS, MEASURING INSTRUMENTS, MICROSCOPY, ORGANIC COMPOUNDS, OXIDES, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, RADIATIONS, SORPTION, SPECTRA, TRANSITION ELEMENT COMPOUNDS
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