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Jani, Kalpesh H.; Chhantbar, M.C.; Joshi, H.H., E-mail: khj12@rediffmail.com2008
AbstractAbstract
[en] The spinel solid solution series MnAlxCrxFe2-2xO4 with x=0.0-0.9 in steps of 0.1 was studied using powder X-ray diffraction profile refinement, magnetization measurement at 80 K using an applied magnetic field 3.18x105 A-turn/m, Moessbauer spectroscopy at 300 K and low field AC susceptibility measurements. We have seen that the increase of Cr3+ ions and Al3+ ions in B sites at the cost of Fe3+ ions leads the present system towards the Neel type of collinear ordering of spins. The negative quadruple shifting seen in Moessbauer results and high value of oxygen positional 'u' parameter indicate oblate type of deformation of 3d5 shell. The results indirectly support the theory of 'exchange disorder' of Fe3+ ions in B sites as the cause of the reduction in magnetic moment for MnFe2O4 from Neel type of ordering. There is the emergence of 'spin clusters' in the long-range network of spins as indicated in the ac susceptibility and Moessbauer results at room temperature in x>0.7 compounds
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Source
S0304-8853(08)00363-6; Available from http://dx.doi.org/10.1016/j.jmmm.2008.03.061; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Journal
Journal of Magnetism and Magnetic Materials; ISSN 0304-8853;
; CODEN JMMMDC; v. 320(18); p. 2208-2214

Country of publication
ALUMINIUM COMPOUNDS, ALUMINIUM IONS, CHROMIUM COMPOUNDS, CHROMIUM IONS, DEFORMATION, FERRITES, IRON IONS, MAGNETIC FIELDS, MAGNETIC MOMENTS, MAGNETIZATION, MANGANESE COMPOUNDS, MOESSBAUER EFFECT, SOLID SOLUTIONS, SPIN, SPINELS, TEMPERATURE RANGE 0065-0273 K, TEMPERATURE RANGE 0273-0400 K, X-RAY DIFFRACTION
ANGULAR MOMENTUM, CHARGED PARTICLES, COHERENT SCATTERING, DIFFRACTION, DISPERSIONS, FERRIMAGNETIC MATERIALS, HOMOGENEOUS MIXTURES, IONS, IRON COMPOUNDS, MAGNETIC MATERIALS, MATERIALS, MINERALS, MIXTURES, OXIDE MINERALS, OXYGEN COMPOUNDS, PARTICLE PROPERTIES, SCATTERING, SOLUTIONS, TEMPERATURE RANGE, TRANSITION ELEMENT COMPOUNDS
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