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Dos Santos-Garcia, A.J.; Duijn, J. van; Saez-Puche, R.; Heymann, G.; Huppertz, H.; Alario-Franco, M.A., E-mail: antonio.dossantos@pcyta.com, E-mail: maaf@quim.ucm.es2008
AbstractAbstract
[en] The synthesis, structure and microstructure of the IrSr2TbCu2O8 cuprate showing metamagnetic properties are described. The sample was prepared at high temperatures and pressures up to 9.2 GPa. The structure is tetragonal, showing a 1212 type structure, that derives from the classical YBaCuO superconductor structure, replacing the tetracoordinated square planar copper [Cu-O4] in the 'chains' by octahedral [Ir-O6] groups that form a perovskite-like layer in the basal plane of the unit cell. A 'simple' cell, ∼apxapx3ap, where ap is the basic perovskite unit cell parameter (ap∼3.8 A), is supported by X-ray powder diffraction (XRD) and a so-called 'diagonal' one, ∼√2apx√2apx3ap, by SAED; a microdomain texture of latter cell and a series of very interesting extended defects have been observed by HREM. Magnetic susceptibility measurements show a magnetic transition, TN∼6 K, with negative Weiss temperature, that indicates antiferromagnetic interactions among the Tb moments. The magnetic structure has been determined by neutron diffraction. A detailed magnetic study has revealed a metamagnetic behavior, something not previously observed in this type of cuprates. Specific heat and resistivity measurements have also been performed to characterize the transition. - Graphical abstract: Reconstructed image from the SAED of the long c tetragonal axis (3ap) of a IrSr2TbCu2O8 crystal. A unit cell picture is included for comparison. Display Omitted
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S0022-4596(08)00099-6; Available from http://dx.doi.org/10.1016/j.jssc.2008.02.022; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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ANTIFERROMAGNETISM, BARIUM OXIDES, COPPER OXIDES, CRYSTAL DEFECTS, CRYSTALS, CUPRATES, ELECTRON DIFFRACTION, HIGH-TC SUPERCONDUCTORS, IRIDIUM COMPOUNDS, LAYERS, MAGNETIC SUSCEPTIBILITY, MICROSTRUCTURE, NEUTRON DIFFRACTION, PEROVSKITE, PRESSURE RANGE GIGA PA, SPECIFIC HEAT, STRONTIUM COMPOUNDS, SYNTHESIS, TERBIUM COMPOUNDS, TRANSMISSION ELECTRON MICROSCOPY, X-RAY DIFFRACTION, YTTRIUM OXIDES
ALKALINE EARTH METAL COMPOUNDS, BARIUM COMPOUNDS, CHALCOGENIDES, COHERENT SCATTERING, COPPER COMPOUNDS, CRYSTAL STRUCTURE, DIFFRACTION, ELECTRON MICROSCOPY, MAGNETIC PROPERTIES, MAGNETISM, MICROSCOPY, MINERALS, OXIDE MINERALS, OXIDES, OXYGEN COMPOUNDS, PEROVSKITES, PHYSICAL PROPERTIES, PRESSURE RANGE, RARE EARTH COMPOUNDS, REFRACTORY METAL COMPOUNDS, SCATTERING, SUPERCONDUCTORS, THERMODYNAMIC PROPERTIES, TRANSITION ELEMENT COMPOUNDS, TYPE-II SUPERCONDUCTORS, YTTRIUM COMPOUNDS
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