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AbstractAbstract
[en] Silver platinum binary alloys with compositions between about Ag2Pt98 and Ag95Pt5 at <∼ 400 deg. C have largely not been observed in bulk due to the large immiscibility between these two metals. We present in this paper that Ag-Pt alloy nanostructures can be made in a broad composition range. The formation of Ag-Pt nanostructures is studied by powder X-ray diffraction (PXRD) and energy-dispersive X-ray (EDX). Our results indicate that lattice parameter changes almost linearly with composition in these Ag-Pt nanomaterials. In another word, lattice parameter and composition relationship follows the Vegard's law, which is a strong indication for the formation of metal alloys. Our transmission electron microscopy (TEM) study shows that the silver-rich Ag-Pt alloy nanostructures have spherical shape, while the platinum-rich ones possess wire-like morphology. The stability and crystal phase are investigated by annealing the alloy nanostructures directly or on carbon supports. - Graphical abstract: While platinum and silver cannot form a solid solution with the composition between about Ag2Pt98 and Ag95Pt5 at 400 deg. C or below in bulk form, alloy particles and wires can be made within this miscibility gap at the nanometer scale
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S0022-4596(08)00141-2; Available from http://dx.doi.org/10.1016/j.jssc.2008.03.013; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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