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AbstractAbstract
[en] A vertical section at 33.3 at.% Y in the Au-Ag-Y ternary system was studied using X-ray diffraction analysis, differential thermal analysis, and optical microscopy. An allotropic phase transformation of the Au2Y phase in the Au-Y binary system is found. The Au2Y phase transforms from a room temperature phase α to a high-temperature modification β at about 778 deg. C. The α-Au2Y has a tetragonal MoSi2-type structure with the lattice parameters a = 0.3692 nm, c = 0.8981 nm; the β-Au2Y has an orthorhombic CeCu2-type structure with the lattice parameters a = 0.4658 nm, b = 0.7340 nm, and c = 0.8200 nm. No allotropic phase transformation of the Ag2Y phase in the Ag-Y binary system is found. The vertical section of the Au2Y-Ag2Y in the Au-Ag-Y ternary phase diagram established on the basis of these studies consists of seven phase regions: L (liquid phase region), α (MoSi2-type structure), β (CeCu2-type structure), α + β, α + L, β + L, and α + β + L
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S0925-8388(06)02136-0; Available from http://dx.doi.org/10.1016/j.jallcom.2006.12.019; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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