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AbstractAbstract
[en] The crystal and local atomic structure of monoclinic ReO2 (α-ReO2) under hydrostatic pressure up to 1.2 GPa was investigated for the first time using both X-ray absorption spectroscopy and high-resolution synchrotron X-ray powder diffraction and a home-built B4C anvil pressure cell developed for this purpose. Extended X-ray absorption fine-structure (EXAFS) data analysis at pressures from ambient up to 1.2 GPa indicates that there are two distinct Re-Re distances and a distorted ReO6 octahedron in the α-ReO2 structure. X-ray diffraction analysis at ambient pressure revealed an unambiguous solution for the crystal structure of the α-phase, demonstrating a modulation of the Re-Re distances. The relatively small portion of the diffraction pattern accessed in the pressure-dependent measurements does not allow for a detailed study of the crystal structure of α-ReO2 under pressure. Nonetheless, a shift and reduction in the (011) Bragg peak intensity between 0.4 and 1.2 GPa is observed, with correlation to a decrease in Re-Re distance modulation, as confirmed by EXAFS analysis in the same pressure range. This behavior reveals that α-ReO2 is a possible inner pressure gauge for future experiments up to 1.2 GPa. (orig.)
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Available from: http://dx.doi.org/10.1107/S0909049508036029
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Journal Article
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Numerical Data
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ABSORPTION SPECTRA, BOND LENGTHS, BRAGG REFLECTION, DEBYE-SCHERRER METHOD, EXPERIMENTAL DATA, FINE STRUCTURE, LATTICE PARAMETERS, MODULATION, MONOCLINIC LATTICES, PRESSURE DEPENDENCE, PRESSURE RANGE GIGA PA, PRESSURE RANGE KILO PA, PRESSURE RANGE MEGA PA 01-10, PRESSURE RANGE MEGA PA 100-1000, PRESSURE RANGE MEGA PA 10-100, RHENIUM OXIDES, SPACE GROUPS, SPECTRAL SHIFT, X-RAY DIFFRACTION, X-RAY SPECTRA
CHALCOGENIDES, COHERENT SCATTERING, CRYSTAL LATTICES, CRYSTAL STRUCTURE, DATA, DIFFRACTION, DIFFRACTION METHODS, DIMENSIONS, INFORMATION, LENGTH, NUMERICAL DATA, OXIDES, OXYGEN COMPOUNDS, PRESSURE RANGE, PRESSURE RANGE MEGA PA, REFLECTION, REFRACTORY METAL COMPOUNDS, RHENIUM COMPOUNDS, SCATTERING, SPECTRA, SYMMETRY GROUPS, TRANSITION ELEMENT COMPOUNDS
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