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[en] The 450 deg. C isothermal section of the Zn-Fe-Bi ternary phase diagram has been determined experimentally using scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDS) and X-ray powder diffraction (XRD). Five three-phase regions exist in the 450 deg. C isothermal section. Experimental results indicate that Bi is almost insoluble in the four Fe-Zn intermetallic compounds and in α-Fe phase, and the solid solubility of Fe in Bi-rich phase is also limited at 450 deg. C
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