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Liu Huaran; Zheng Wenming; Yan Xin; Feng Boxue, E-mail: fengbx@lzu.edu.cn2008
AbstractAbstract
[en] The non-stoichiometric nickel oxide (NiOx, x > 1) films deposited on a conducting substrate by RF magnetron sputtering have been investigated for electrochromism in alkaline solution. It was found that both Ni3+ and Ni2+ existed in NiOx films. The intercalation and deintercalation of H+ ions causes the bleaching and coloring of NiOx films. The atomic ratio of Ni and O in the NiOx films is 0.7:1 (as-deposited); 0.51:1 (bleached); 0.45:1 (colored). The maximal optical density change was found to be 0.78 at a spectral of 326 nm. With the increase of temperature of heat treatment, the electrochromic properties of NiOx films were weakened
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S0925-8388(07)01722-7; Available from http://dx.doi.org/10.1016/j.jallcom.2007.08.066; Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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