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AbstractAbstract
[en] Dielectric spectroscopy has been applied to investigate the electrical properties of tungsten bronze ferroelectric ceramics of Pb0.77K0.115Sm0.115Nb2O6 (Sm:PKN) over a wide frequency (45 Hz to 5 MHz) and temperature (35-600 deg. C) range. XRD analysis showed the lattice parameters, a = 17.731 A, b = 18.035 A and c = 3.843 A. Determined the piezoelectric constants, Kp = 18%, Kt = 21%, d33 = 68, and quality factor (Qm) = 38, reveals the material may be useful for transducer applications. Similar peak positions of normalized electrical modulus and impedance plots indicate the long range conductivity in Sm:PKN. Cole-Cole plots observed to be non-Debye type with polydispersive in nature. Determined the coefficient A(T) = {a(T)S/L}, the exponent n(T) fitted the Jonscher's dielectric dispersion relations for εI with experimental data. Parameters n(T) and A(T) showed an anomaly at the vicinity of TC, respectively. dc and ac conduction activation energies are estimated from Arrhenius plots. Compared the results from different techniques, and discussed the conduction mechanism in the material
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S0925-8388(07)01972-X; Available from http://dx.doi.org/10.1016/j.jallcom.2007.10.023; Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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ACTIVATION ENERGY, CERAMICS, DIELECTRIC PROPERTIES, DISPERSION RELATIONS, FERROELECTRIC MATERIALS, HZ RANGE, IMPEDANCE, KHZ RANGE, LATTICE PARAMETERS, MHZ RANGE, NIOBATES, PIEZOELECTRICITY, POTASSIUM COMPOUNDS, QUALITY FACTOR, SAMARIUM COMPOUNDS, SPECTROSCOPY, TEMPERATURE RANGE 0273-0400 K, TEMPERATURE RANGE 0400-1000 K, TUNGSTEN BRONZE, X-RAY DIFFRACTION
ALKALI METAL COMPOUNDS, ALLOYS, COHERENT SCATTERING, COPPER ALLOYS, COPPER BASE ALLOYS, DIELECTRIC MATERIALS, DIFFRACTION, DIMENSIONLESS NUMBERS, ELECTRICAL PROPERTIES, ELECTRICITY, ENERGY, FREQUENCY RANGE, MATERIALS, NIOBIUM COMPOUNDS, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, RARE EARTH COMPOUNDS, REFRACTORY METAL COMPOUNDS, SCATTERING, TEMPERATURE RANGE, TRANSITION ELEMENT ALLOYS, TRANSITION ELEMENT COMPOUNDS, TUNGSTEN ALLOYS
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