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Grigiante, Maurizio; Stringari, Paolo; Scalabrin, Giancarlo; Ihmels, E. Christian; Fischer, Kai; Gmehling, Juergen, E-mail: gscala@unipd.it2008
AbstractAbstract
[en] A static VLE apparatus has been used for the measurement of the (vapour + liquid + liquid) equilibrium of the (propylene + isopropanol + water) system at T = 313.15 K and pressures between (1.381 and 1.690) MPa. Using an isothermal flow calorimeter, HE values have been obtained for the binary system (isopropanol + water) over the temperature range from (313.15 to 353.15) K and pressures from (3.8 to 4.19) MPa. For the pseudo-binary mixture (propylene + (isopropanol + water)), HE values have been measured in the temperature range from (313.15 to 353.15) K and pressures from (1.997 to 5.89) MPa. This last mixture was studied starting from (isopropanol + water) at 0.25, 0.50, and 0.75 molar compositions in isopropanol. The new data, together with the available phase equilibrium and HE data from the literature, have been regressed by a conventional GE-EoS model reaching satisfactory results, except for the VLLE representation
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S0021-9614(07)00237-6; Available from http://dx.doi.org/10.1016/j.jct.2007.12.002; Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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