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AbstractAbstract
[en] The microstructure and magnetic properties have been investigated systematically for Sn1-xMnxO2 (0 ≤ x ≤ 7%) nanoparticles synthesized by chemical co-precipitation method. The X-ray diffraction reveals that all samples are pure rutile-type tetragonal phase and the cell parameters a and c decrease monotonously with the increase of Mn content, indicated that Mn ions substitute into the lattice of SnO2. X-ray photoelectron suggests that Mn ions behave as the mixture state of Mn3+ and Mn4+ in samples. Magnetic investigations demonstrate that magnetic properties strongly depend on both the sintering temperature and doping content. No ferromagnetism is observed for samples sintered at high temperature (TS = 800 deg. C), irrespective of the doping content. In contrast, the samples sintered at low temperature (TS = 450 deg. C) possess room temperature ferromagnetism when the doping content is below 5%. A plausible explanation of the magnetic properties is presented in terms of bound magnetic polaron model
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Source
S0925-8388(07)02191-3; Available from http://dx.doi.org/10.1016/j.jallcom.2007.11.054; Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Journal
Country of publication
COPRECIPITATION, DOPED MATERIALS, FERROMAGNETISM, MAGNETIC PROPERTIES, MAGNETIC SEMICONDUCTORS, MANGANESE COMPOUNDS, MANGANESE IONS, MICROSTRUCTURE, NANOSTRUCTURES, PARTICLES, SINTERING, TEMPERATURE RANGE 0273-0400 K, TEMPERATURE RANGE 0400-1000 K, TEMPERATURE RANGE 1000-4000 K, TIN OXIDES, X-RAY DIFFRACTION
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