Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.011 seconds
AbstractAbstract
[en] Traditional ligand-field theory has to be improved by taking into account both pure electronic contribution and electron-phonon interaction one (including lattice-vibrational relaxation energy). By means of improved ligand-field theory, the R line, t322T1 and t322T2 lines, t22 (3T1)e4T2,t22(3T1)e4T1 and t2e2(4A2)4T1 bands, g factors of t324A2 and t232 E, four strain-induced level-splittings and R-line thermal shift of MgO:V2+ have been calculated. The results are in very good agreement with the experimental data. It is found that for MgO:V2+, the contributions due to electron-phonon interaction (EPI) come from the first-order term; the contributions from the second-order and higher terms are insignificant. In thermal shift of R line of MgO:V2+, the temperature-dependent contribution due to EPI is dominant. The results obtained in this work may be used in theoretical calculations of other effects of EPI
Primary Subject
Source
Available from http://dx.doi.org/10.1088/0253-6102/50/2/47; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Journal
Communications in Theoretical Physics; ISSN 0253-6102;
; v. 50(2); p. 511-516

Country of publication
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue