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Dubey, K.A.; Bhardwaj, Y.K.; Chaudhari, C.V.; Sabharwal, S.
Proceedings of second DAE-BRNS international symposium on materials chemistry2008
Proceedings of second DAE-BRNS international symposium on materials chemistry2008
AbstractAbstract
[en] Full text: EVA is widely used as an insulating material for high voltage cables and in the footwear and toy industries due to its high flexibility and chemical inertness. The nano-composites of EVA with MWNT are of the special interest because incorporation of suitable amount of MWNT in EVA matrix is expected to significantly enhance EVA's thermal and mechanical properties, and open a new domain of applications. The modification of EVA by using high-energy radiation and with particulate filler has been widely practiced; however, there is not much information available on the radiation processing of EVA nanocomposites. To understand the effect of radiation and of MWNT addition on the physico-mechanical characteristics of EVA, different compositions of ethylene vinyl acetate (EVA)/multiple walled carbon nanotube (MWNT) nanocomposites were prepared by mixing in Brabender and subjected to different doses of gamma radiation. The efficiency of radiation vulcanization was analyzed by gel-content, Charlesby-Pinner parameter and crosslinking density measurements. Gamma radiation induced crosslinking was found to increase with MWNT fraction in EVA/MWNT nanocomposites (Po/qo range: 1.15-0.98). These results ruled out the possibility of a significant neutralization of single ionization spurs by MWNT addition. The polymer-filler interaction parameter determined from Kraus plot indicated good interaction between EVA and MWNTs. Storage modulus changed from 7 x 107 Pa to 1.8 x 108 Pa with incorporation of 5% (wt/wt) MWNT while density increased from 0.78 g/cc to 0.80 g/cc
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Nigam, S.; Banerjee, A.M.; Bhattacharyya, K.; Varma, S.; Bharadwaj, S.R.; Jain, V.K.; Das, D. (Chemistry Division, Bhabha Atomic Research Centre, Mumbai (India)) (eds.); Society for Materials Chemistry, Chemistry Division, Bhabha Atomic Research Centre, Mumbai (India); Board of Research in Nuclear Sciences, Dept. of Atomic Energy, Mumbai (India); 504 p; ISBN 81-88513-26-1;
; Dec 2008; p. 426; ISMC-08: 2. DAE-BRNS international symposium on materials chemistry; Mumbai (India); 2-6 Dec 2008

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