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Cheng Shuying; He Yingjie; Chen Guonan, E-mail: gnchen@fzu.edu.cn2008
AbstractAbstract
[en] SnS thin films were deposited onto indium tin oxide (ITO) glass substrates by constant potential cathodic electro-deposition from aqueous solution containing stannous sulfate, ethylenediamine tetraacetate acid and sodium thiosulfate. The co-deposited potential was explored by cyclic voltammetry and the deposition potential (E) was roughly determined to be more negative than -0.70 V (vs. saturated calomel electrode, SCE). The analysis of the composition of the as-deposited films by X-ray fluorescence spectrometer indicated that stoichiometric SnS films could be obtained under the condition of E = -0.95 to -1.00 V. The films deposited at E = -1.00 V were characterized with X-ray diffraction (XRD), scanning electron microscope (SEM), and their transmission and reflectance spectra were measured. The as-deposited films were polycrystalline SnS compound with orthorhombic crystalline structure and the ratio of Sn and S was nearly 1. The films were uniform and compact with small grains. The direct band gap of the films was estimated to be about 1.10-1.43 eV with an absorption coefficient near the fundamental absorption edge larger than 4 x 104 cm-1
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S0254-0584(08)00122-3; Available from http://dx.doi.org/10.1016/j.matchemphys.2008.03.004; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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AMINO ACIDS, CARBOXYLIC ACIDS, CHALCOGENIDES, CHELATING AGENTS, COHERENT SCATTERING, CRYSTAL LATTICES, CRYSTAL STRUCTURE, CRYSTALS, DEPOSITION, DIFFRACTION, DISPERSIONS, ELECTROLYSIS, ELECTRON MICROSCOPY, EMISSION, ENERGY RANGE, EV RANGE, FILMS, HOMOGENEOUS MIXTURES, INDIUM COMPOUNDS, LUMINESCENCE, LYSIS, MEASURING INSTRUMENTS, MICROSCOPY, MIXTURES, ORGANIC ACIDS, ORGANIC COMPOUNDS, OXIDES, OXYGEN COMPOUNDS, PHOTON EMISSION, SCATTERING, SOLUTIONS, SORPTION, SULFATES, SULFUR COMPOUNDS, SURFACE COATING, TIN COMPOUNDS
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