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AbstractAbstract
[en] Co-Ni-P alloy thin films have been electrodeposited from sulfate baths at various solution pH and current density values. The effect of pH and current density on compositional, structural, morphological, and magnetic properties of these films was investigated by EDAX (energy dispersive analysis of X-ray spectroscopy), XRD (X-ray diffractometer system), AFM (atomic force microscope) and VSM (vibrating sample magnetometer). The reaction mechanism of individual deposition of Co, Ni and Co-Ni-P were investigated by cyclic voltammetry. The EDAX results revealed that cobalt and phosphorous content were high and nickel content was low at high solution pH and at low current density. X-ray diffraction studies exhibit that the intensity of hcp and Co-Ni-P amorphous phases increases and the intensity of fcc phase decreased when increasing the solution pH and decreasing the value of current density. The surface morphology of the films were observed by AFM. The deposited films exhibit hard magnetic properties at high pH value and soft magnetic properties at low pH value
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S0254-0584(08)00331-3; Available from http://dx.doi.org/10.1016/j.matchemphys.2008.05.080; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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AMORPHOUS STATE, ATOMIC FORCE MICROSCOPY, COBALT ALLOYS, COERCIVE FORCE, CURRENT DENSITY, ELECTRODEPOSITION, FCC LATTICES, HCP LATTICES, MAGNETIC PROPERTIES, MORPHOLOGY, NICKEL ALLOYS, PH VALUE, PHOSPHORUS ADDITIONS, REACTION KINETICS, SULFATES, SURFACES, THIN FILMS, VIBRATING SAMPLE MAGNETOMETERS, VOLTAMETRY, X-RAY DIFFRACTION, X-RAY DIFFRACTOMETERS, X-RAY SPECTROSCOPY
ALLOYS, COHERENT SCATTERING, CRYSTAL LATTICES, CRYSTAL STRUCTURE, CUBIC LATTICES, DEPOSITION, DIFFRACTION, DIFFRACTOMETERS, ELECTROLYSIS, FILMS, HEXAGONAL LATTICES, KINETICS, LYSIS, MAGNETOMETERS, MEASURING INSTRUMENTS, MICROSCOPY, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, SCATTERING, SPECTROSCOPY, SULFUR COMPOUNDS, SURFACE COATING, TRANSITION ELEMENT ALLOYS
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