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Suyama, Tadahiro; Ueno, Kenichi; Sasamoto, Hiroshi
Japan Atomic Energy Agency, Tokai, Ibaraki (Japan)2008
Japan Atomic Energy Agency, Tokai, Ibaraki (Japan)2008
AbstractAbstract
[en] To evaluate long term behavior of corrosion for carbon steel in compacted bentonite, and to evaluate long term stability of bentonite, corrosion experiments were conducted using synthetic sea water and synthetic groundwater at 50 and 80degC for 10 years under anaerobic atmosphere. In the present study, the samples of compacted bentonite after experiments were investigated to understand the alteration behavior of bentonite by iron-bentonite interactions. Results were summarized below. Iron generated by corrosion of carbon steel was migrated into compacted bentonite further in the synthetic seawater case than in the synthetic groundwater case. Result of TEM observation for the sample of synthetic sea water case at 80degC showed that the original layer structure for clay minerals was maintained and the layer distance was about 12[A] which was similar to the layer distance of normal 2:1 smectite. Thus, it was suggested that there was no change in smectite before and after experiments. Iron generated by corrosion of carbon steel was migrated into compacted bentonite in anaerobic condition case but scarcely migrated in aerobic condition case. Results of EPMA analysis indicated that the maximum migration depth of iron in compacted bentonite was about 0.2 mm for sample in synthetic sea water at 80degC under anaerobic condition. Results of XRD analysis for the sample in which iron migration in compacted bentonite was observed showed that there was no corrosion product in compacted bentonite and the structure of clay mineral in bentonite was di-octahedral. Furthermore, the result of XRD analysis under relative humidity controlled condition suggested that the swelling property of sample after experiment was similar to that of initial Na-type smectite. Therefore, it was supposed that the initial Na-type smectite did not change during the experiment. Batch type experiments with different temperature, solutions and duration have been conducted to understand the alteration behavior of bentonite by interactions with iron material in our previous studies. According to the results of batch type experiments, some changes like ion type change from Na to Fe type smectite and production of very small amount of non-swelling minerals etc. were identified after experiments. However, no change was identified for the present study using compacted bentonite, although the iron migration in compacted bentonite was observed. In conclusion, in order to evaluate the iron-bentonite interactions in compacted system like repository conditions, it would be important not to utilize directly the results by batch type experiments but understand the phenomena which would be occurred in compacted bentonite. (author)
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Mar 2008; 54 p; Also available from JAEA; URL: http://dx.doi.org/10.11484/JAEA-Data-Code-2008-007; 13 refs., 53 figs., 7 tabs., 1 photo
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Report
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ALLOYS, CARBON ADDITIONS, CHEMICAL REACTIONS, CLAYS, COHERENT SCATTERING, DIFFRACTION, DISSOLUTION, ELECTRON MICROSCOPY, HYDROGEN COMPOUNDS, INORGANIC ION EXCHANGERS, ION EXCHANGE MATERIALS, IRON ALLOYS, IRON BASE ALLOYS, JAPANESE ORGANIZATIONS, MANAGEMENT, MATERIALS, METAMORPHISM, MICROSCOPY, MINERALS, NATIONAL ORGANIZATIONS, OXYGEN COMPOUNDS, SCATTERING, SEPARATION PROCESSES, SILICATE MINERALS, STEELS, TRANSITION ELEMENT ALLOYS, WASTE DISPOSAL, WASTE MANAGEMENT, WATER
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