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Apted, Michael J.; Bennett, David G.; Saario, Timo
Swedish Radiation Safety Authority, Stockholm (Sweden)2009
Swedish Radiation Safety Authority, Stockholm (Sweden)2009
AbstractAbstract
[en] The planned spent nuclear fuel repository in Sweden relies on a copper cast iron canister as the primary engineered barrier. The corrosion behaviour of copper in the expected environment needs to be thoroughly understood as a basis for the post-closure safety analysis. It has been shown that corrosion may indeed be the primary canister degradation process during the utilised assessment period of 1 million years (this period is the longest time for which risk calculations will be needed according guidelines issued by the Swedish Radiation Safety Authority). Previous analysis work has been based on that copper is corroded during the initial oxic environment as well as by sulphide in groundwater once reducing conditions have been restored. The quantitative analyses of these processes consider upper-bound amounts of atmospheric oxidation as well as representative sulphide concentrations coupled with the transport limitation of the bentonite buffer and of the surrounding bedrock. A group of researchers at the Royal Institute of Technology (KTH), Stockholm, Sweden suggest, based on published experimental results, that disposed canisters will also be corroded by water itself under hydrogen evolution. The purpose of the project is to evaluate the findings of the KTH research group based on an assessment of their experimental methods and chemical analysis work, thermodynamic models, and a discussion of reaction mechanisms as well as comparison with the analogue behaviour of native copper. As a background, the authors also provide a brief overview of other corrosion processes and safety assessment significance. The authors conclude that the KTH researchers have not convincingly demonstrated that copper will indeed be corroded by pure water and that it is in any case very unlikely that this process will be dominant under the reducing chemical conditions that are expected in the repository environment. How-ever, the authors do not completely rule out that copper may corrode slowly by extracting oxygen from water in pure water at atmospheric conditions. They therefore recommend that an independent experimental investigation of the postulated corrosion process should be carried out
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Sep 2009; 44 p; ISSN 2000-0456;
; PROJECT SSM 1724; Also available from: http://www.stralsakerhetsmyndigheten.se/In-English/Publ; 29 refs., 8 figs., 3 tabs.

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