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[en] We investigated the evolution of experimental two-neutron separation energies (S2n) along the isotopic chains for the even-even nuclei. In order to enhance the sensitivity of our search, differential variation of the S2n has been investigated. The emphasis is on finding nonmonotonic behaviors which can be correlated with phase/shape transition. Correlations of the ground state S2n values with the excited states energies R4/2 ratio are also discussed.