Dielectric response of novel one-dimensional hydrogen-bonded molecular crystal [4,6-dmpH][Hca]

Ohchi, Hironori; Takahashi, Kazuyuki; Yamaura, Jyun-ichi; Takaishi, Shinya; Mori, Hatsumi

doi:10.1016/j.physb.2009.12.047

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Dielectric response of novel one-dimensional hydrogen-bonded molecular crystal [4,6-dmpH][Hca]

Ohchi, Hironori; Takahashi, Kazuyuki; Yamaura, Jyun-ichi; Takaishi, Shinya; Mori, Hatsumi2010

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AbstractAbstract

[en] The frequency dependent dielectric response due to proton transfer is observed for the novel one-dimensional (1D) hydrogen-bonded co-crystal, [4,6-dmpH][Hca] (4,6-dmp=4,6-dimethylpyrimidine, ca=chloranilic acid). This response is only observed for an as-grown crystal in a metastable state with defects of hydrogen bonds. The critical hydrogen-bond length and one-dimensionality might be deeply related to the metastable state.

Primary Subject

CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY (S75)

Source

8. international symposium on crystalline organic metals, superconductors and ferromagnets; Hokkaido (Japan); 12-17 Sep 2009; Yamada conference LXIV - ISCOM 2009; Hokkaido (Japan); 12-17 Sep 2009; S0921-4526(09)01519-1; Available from http://dx.doi.org/10.1016/j.physb.2009.12.047; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)

Record Type

Journal Article

Literature Type

Conference

Journal

Physica. B, Condensed Matter; ISSN 0921-4526;

; CODEN PHYBE3; v. 405(11); p. S341-S343

Country of publication

Netherlands

Descriptors (DEI)

BOND LENGTHS, CHLORANILIC ACID, DIELECTRIC MATERIALS, FREQUENCY DEPENDENCE, HYDROGEN, METASTABLE STATES, MOLECULAR CRYSTALS, ONE-DIMENSIONAL CALCULATIONS, PROTONS

Descriptors (DEC)

AROMATICS, BARYONS, BENZOQUINONES, CRYSTALS, DIMENSIONS, ELEMENTARY PARTICLES, ELEMENTS, ENERGY LEVELS, EXCITED STATES, FERMIONS, HADRONS, LENGTH, MATERIALS, NONMETALS, NUCLEONS, ORGANIC COMPOUNDS, ORGANIC OXYGEN COMPOUNDS, QUINONES

LanguageLanguage

English

Reference NumberReference Number

41132459

INIS VolumeINIS Volume

INIS IssueINIS Issue

External URLExternal URL

http://dx.doi.org/10.1016/j.physb.2009.12.047

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