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AbstractAbstract
[en] We report an effective method to synthesize a red long-lasting phosphorescent material, Y2O2S: Eu3+, Mg2+, Ti4+ nanotubes. Y(OH)3 nanotubes were first synthesized by a convenient hydrothermal method to serve as the precursor. Y2O2S: Eu3+, Mg2+, Ti4+ powders were obtained with high yield and purity by calcinating the precursor in CS2 atmosphere. The morphology and optical properties of the composites were characterized. XRD investigation showed a pure phase of Y2O2S. SEM and TEM observation revealed that the phosphors with diameters of 100-200 nm and lengths of 1-3 μm inherited the tube-like shape from the precursor after being calcinated in CS2 atmosphere. From the spectrum, the main emission peaks are ascribed to Eu3+ ions transition from 5DJ (J=0, 1, 2) to 7FJ (J=0, 1, 2, 3, 4). After irradiation by 265 or 325 nm, the phosphor emitted red color long-lasting phosphorescence. It was considered that the red-emitting long-lasting phosphorescence was due to the persistent energy transfer from the traps to the Ti4+ and Mg2+ ions.
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S0921-4526(10)00475-8; Available from http://dx.doi.org/10.1016/j.physb.2010.05.005; Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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CARBON SULFIDES, CESIUM SULFIDES, DOPED MATERIALS, EUROPIUM ADDITIONS, HYDROTHERMAL SYNTHESIS, MAGNESIUM ADDITIONS, NANOTUBES, OXYSULFIDES, PHOSPHORESCENCE, PHOSPHORS, POWDERS, SCANNING ELECTRON MICROSCOPY, SPECTRA, TITANIUM ADDITIONS, TRANSMISSION ELECTRON MICROSCOPY, X-RAY DIFFRACTION, YTTRIUM OXIDES
ALKALI METAL COMPOUNDS, ALLOYS, CARBON COMPOUNDS, CESIUM COMPOUNDS, CHALCOGENIDES, COHERENT SCATTERING, DIFFRACTION, ELECTRON MICROSCOPY, EMISSION, EUROPIUM ALLOYS, LUMINESCENCE, MAGNESIUM ALLOYS, MATERIALS, MICROSCOPY, NANOSTRUCTURES, OXIDES, OXYGEN COMPOUNDS, PHOTON EMISSION, RARE EARTH ADDITIONS, RARE EARTH ALLOYS, SCATTERING, SULFIDES, SULFUR COMPOUNDS, SYNTHESIS, TITANIUM ALLOYS, TRANSITION ELEMENT ALLOYS, TRANSITION ELEMENT COMPOUNDS, YTTRIUM COMPOUNDS
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