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AbstractAbstract
[en] The temperature dependence of vibration spectra of one SbSBr chain (nanowire) in the direction of the c(z)-axis has been calculated in quasiharmonic approximation by diagonalization of dynamical matrix. The vibrational frequencies in the direction of c(z)-axis have been derived by fitting of the experimental low-frequency ωs2 of soft infrared (IR) mode of bulk-size SbSBr with the theoretical quasiharmonic low-frequency ω2 of SbSBr nanowires. In this work the nature of anharmonism and temperature dependence of force constants between atoms in SbSBr crystal along c(z)-axis have been discussed. The anharmonism of all soft (at BZ k=0) modes has been created by the interaction between phonons.
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S0921-4526(10)00521-1; Available from http://dx.doi.org/10.1016/j.physb.2010.05.048; Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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