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AbstractAbstract
[en] Multiferroic nanoceramics BiFe1-xNixO3 (where x=0, 0.15, 0.20, and 0.25) were prepared by the sol-gel method. XRD analysis of samples calcined at a low temperature of 400 deg. C for 2 h shows the formation of a single phase perovskite rhombohedral structure. Average particle size was observed to be ∼50 nm by TEM measurement. Magnetization was found to increase with increase in the concentration of Ni. Dielectric constant and dielectric loss were measured up to 1 MHz frequency. Variation of dielectric constant with temperature shows a peak at ∼395 deg. C (Neel temperature) for x=0.15 and the peak shifts towards lower temperature at a higher concentration of Ni with diffused type of phase transition. Magnetocapacitance was found to decrease with magnetic field. For BiFe1-xNixO3 (with x=0.15, 0.20, 0.25) nanoceramics, the fractional change of the magnetic field induced a change in the dielectric constant, which may well be approximated by Δε/ε=γM2, (where γ (magnetoelectric interaction ) is small and negative). A linear fit gave the value of γ of ∼-2.14x10-3, -2.11x10-3, and -2.09x10-3 for BiFe1-xNixO3 nanoceramics, with x=0.15, 0.20, and 0.25, respectively.
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S0921-4526(10)00824-0; Available from http://dx.doi.org/10.1016/j.physb.2010.08.054; Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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BISMUTH COMPOUNDS, CERAMICS, CRYSTAL STRUCTURE, DIELECTRIC MATERIALS, IRON COMPOUNDS, MAGNETIC FIELDS, MAGNETIC PROPERTIES, MAGNETIZATION, NANOSTRUCTURES, NEEL TEMPERATURE, NICKEL COMPOUNDS, OXYGEN COMPOUNDS, PARTICLE SIZE, PERMITTIVITY, PEROVSKITE, PHASE TRANSFORMATIONS, SOL-GEL PROCESS, TRANSMISSION ELECTRON MICROSCOPY, TRIGONAL LATTICES, X-RAY DIFFRACTION
COHERENT SCATTERING, CRYSTAL LATTICES, CRYSTAL STRUCTURE, DIELECTRIC PROPERTIES, DIFFRACTION, ELECTRICAL PROPERTIES, ELECTRON MICROSCOPY, MATERIALS, MICROSCOPY, MINERALS, OXIDE MINERALS, PEROVSKITES, PHYSICAL PROPERTIES, SCATTERING, SIZE, THERMODYNAMIC PROPERTIES, TRANSITION ELEMENT COMPOUNDS, TRANSITION TEMPERATURE
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