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Park, T.J.; Wong, S.; Papaefthymiou, G.C.; Viescas, A.J.; Lee, Y.; Zhou, H.
Brookhaven National Laboratory (United States). Funding organisation: DOE - Office Of Science (United States)2010
Brookhaven National Laboratory (United States). Funding organisation: DOE - Office Of Science (United States)2010
AbstractAbstract
[en] We report on the Moessbauer spectra and magnetization properties of single-crystalline (BiFeO3)x-(BaTiO3)1-x solid solution nanostructures in the form of nanocubes, measuring approximately 150 to 200 nm on a side, prepared by a molten salt solid-state reaction method in the compositional range wherein 0.5 (le) x (le) 1. Powder x-ray diffraction (XRD) and monochromatic synchrotron XRD studies indicate products of high purity, which undergo gradual, well-controlled structural transformations from rhombohedral to tetragonal structures with decreasing 'x.' For all solid solution products, room-temperature magnetization studies exhibit hysteretic behavior with remnant magnetization values of Mr (ge) 0.32 emu/g, indicating that the latent magnetization locked within the toroidal spin structure of BiFeO3 has been released. Room-temperature Moessbauer spectra show composition-dependent characteristics with decreasing magnetic hyperfine field values and increasing absorption linewidths due to a decrease in the magnetic exchange interaction strength with decreasing x. For the lowest x=0.5 composition studied, the Moessbauer spectra show paramagnetic behavior, indicating a Neel temperature for this composition below 300 K. However, room-temperature magnetization studies with applied fields of up to 50 kOe show hysteretic behavior for all compositions, including the x=0.5 composition, presumably due to field-induced ordering. Furthermore, hysteresis loops for all compositions exhibit smaller coercivities at 10 K than at 300 K, an observation that may suggest the presence of magnetoelectric coupling in these systems.
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Source
BNL--93826-2010-JA; KC0202020; AC02-98CH10886; ISSN 1550-235X; 

Record Type
Journal Article
Journal
Physical Review. B, Condensed Matter and Materials Physics; ISSN 1098-0121;
; v. 82(2); p. 024431

Country of publication
ALKALINE EARTH METAL COMPOUNDS, ANGULAR MOMENTUM, CHALCOGENIDES, COHERENT SCATTERING, DIFFRACTION, DISPERSIONS, HOMOGENEOUS MIXTURES, INTERACTIONS, IRON COMPOUNDS, MIXTURES, OXIDES, OXYGEN COMPOUNDS, PARTICLE PROPERTIES, PHYSICAL PROPERTIES, SALTS, SCATTERING, SOLUTIONS, SORPTION, THERMODYNAMIC PROPERTIES, TITANIUM COMPOUNDS, TRANSITION ELEMENT COMPOUNDS, TRANSITION TEMPERATURE
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