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Vasudevamurthy, Gokul; Katoh, Yutai; Hunn, John D.; Snead, Lance Lewis
Oak Ridge National Laboratory (United States). Funding organisation: ORNL work for others (United States)2010
Oak Ridge National Laboratory (United States). Funding organisation: ORNL work for others (United States)2010
AbstractAbstract
[en] Zirconium carbide is a candidate to either replace or supplement silicon carbide as a coating material in TRISO fuel particles for high temperature gas-cooled reactor fuels. Six sets of ZrC coated surrogate microsphere samples, fabricated by the Japan Atomic Energy Agency using the fluidized bed chemical vapor deposition method, were irradiated in the High Flux Isotope Reactor at the Oak Ridge National Laboratory. These developmental samples available for the irradiation experiment were in conditions of either as-fabricated coated particles or particles that had been heat-treated to simulate the fuel compacting process. Five sets of samples were composed of nominally stoichiometric compositions, with the sixth being richer in carbon (C/Zr = 1.4). The samples were irradiated at 800 and 1250 C with fast neutron fluences of 2 and 6 dpa. Post-irradiation, the samples were retrieved from the irradiation capsules followed by microstructural examination performed at the Oak Ridge National Laboratory's Low Activation Materials Development and Analysis Laboratory. This work was supported by the US Department of Energy Office of Nuclear Energy's Advanced Gas Reactor program as part of International Nuclear Energy Research Initiative collaboration with Japan. This report includes progress from that INERI collaboration, as well as results of some follow-up examination of the irradiated specimens. Post-irradiation examination items included microstructural characterization, and nanoindentation hardness/modulus measurements. The examinations revealed grain size enhancement and softening as the primary effects of both heat-treatment and irradiation in stoichiometric ZrC with a non-layered, homogeneous grain structure, raising serious concerns on the mechanical suitability of these particular developmental coatings as a replacement for SiC in TRISO fuel. Samples with either free carbon or carbon-rich layers dispersed in the ZrC coatings experienced negligible grain size enhancement during both heat treatment and irradiation. However, these samples experienced irradiation induced softening similar to stoichiometric ZrC samples.
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1 Sep 2010; 24 p; AC05-00OR22725; Available from http://info.ornl.gov/sites/publications/files/Pub26564.pdf; PURL: https://www.osti.gov/servlets/purl/989722-aXfWIA/; doi 10.2172/989722
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Report
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CARBON, CHEMICAL VAPOR DEPOSITION, COATINGS, FAST NEUTRONS, FLUIDIZED BEDS, FUEL PARTICLES, GAS COOLED REACTORS, GRAIN SIZE, HEAT TREATMENTS, HFIR REACTOR, HTGR TYPE REACTORS, IRRADIATION, IRRADIATION CAPSULES, JAEA, MICROSPHERES, NUCLEAR ENERGY, ORNL, POST-IRRADIATION EXAMINATION, SILICON CARBIDES, ZIRCONIUM CARBIDES
BARYONS, CARBIDES, CARBON COMPOUNDS, CHEMICAL COATING, DEPOSITION, ELEMENTARY PARTICLES, ELEMENTS, ENERGY, ENRICHED URANIUM REACTORS, FERMIONS, GAS COOLED REACTORS, GRAPHITE MODERATED REACTORS, HADRONS, IRRADIATION REACTORS, ISOTOPE PRODUCTION REACTORS, JAPANESE ORGANIZATIONS, MICROSTRUCTURE, NATIONAL ORGANIZATIONS, NEUTRONS, NONMETALS, NUCLEONS, REACTORS, RESEARCH AND TEST REACTORS, RESEARCH REACTORS, SILICON COMPOUNDS, SIZE, SURFACE COATING, TANK TYPE REACTORS, TEST FACILITIES, TEST REACTORS, THERMAL REACTORS, TRANSITION ELEMENT COMPOUNDS, US AEC, US DOE, US ERDA, US ORGANIZATIONS, WATER COOLED REACTORS, WATER MODERATED REACTORS, ZIRCONIUM COMPOUNDS
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