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AbstractAbstract
[en] We have studied the effect of doping with Eu2+ and Ce3+ ions on the photoluminescence of BaGa2Se4 crystals in the temperature range 77-300 K. We have established that the broad bands with maxima at wavelengths 456 nm and 506 nm observed in the photoluminescence spectra of BaGa2Se4:Ce3+ crystals are due to intracenter transitions 5d→2F7/2 and 5d→2F5/2 of the Ce3+ ions, while the broad photoluminescence band with maximum at 521 nm in the spectrum of BaGa2Se4:Eu2+ is associated with 4f6 5d→4f7 (8S7/2) transitions of the Eu2+ ion. We show that in BaGa2Se4:Eu2+,Ce3+ crystals, excitation energy is transferred from the Ce3+ ions to the Eu2+ ions. Keywords: luminescence, barium selenogallate, rare earth ions, europium, cerium. (authors)
Original Title
Lyuminestsentsiya aktivirovannykh ionami Eu2+ i Ce3+ kristallov BaGa2Se4
Primary Subject
Source
17 refs., 3 figs.
Record Type
Journal Article
Journal
Zhurnal Prikladnoj Spektroskopii; ISSN 0514-7506;
; v. 77(1); p. 124-128

Country of publication
BARIUM COMPOUNDS, CERIUM ADDITIONS, CERIUM IONS, CRYSTALS, DOPED MATERIALS, ENERGY-LEVEL TRANSITIONS, EUROPIUM ADDITIONS, EUROPIUM IONS, GALLIUM COMPOUNDS, LUMINESCENCE, PHOTOLUMINESCENCE, SELENIUM COMPOUNDS, TEMPERATURE DEPENDENCE, TEMPERATURE RANGE 0065-0273 K, TEMPERATURE RANGE 0273-0400 K, WAVELENGTHS
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