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Kitamura, Akira; Kirishima, Akira; Saito, Takumi; Shibutani, Sanae; Tochiyama, Osamu
Japan Atomic Energy Agency, Tokai, Ibaraki (Japan)2010
Japan Atomic Energy Agency, Tokai, Ibaraki (Japan)2010
AbstractAbstract
[en] Within the scope of the JAEA thermodynamic database project for performance assessment of geological disposal of high-level radioactive and TRU wastes, the selection of the thermodynamic data on the inorganic compounds and complexes of molybdenum were carried out. We focused to select thermodynamic data of aqueous species and compounds which could form under repository conditions for the disposal of radioactive wastes, i.e. relatively low concentration of molybdenum and from near neutral through alkaline conditions. Selection of thermodynamic data was based on the guidelines by the Nuclear Energy Agency in the Organisation for Economic Co-operation and Development (OECD/NEA). Extensive literature survey was performed and all the obtained articles were carefully reviewed to select the thermodynamic data for molybdenum. Thermodynamic data at 25degC and zero ionic strength were determined from accepted thermodynamic data which were considered to be reliable. We especially paid attention to select formation constant of molybdate ion (MoO42-) with hydrogen ion (H+) in detail. This is the first report in showing selection of thermodynamic data for molybdenum with detailed reviewing process. (author)
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Jun 2010; 86 p; Also available from JAEA; URL: http://dx.doi.org/10.11484/JAEA-Review-2010-010; 57 refs., 4 figs., 11 tabs.
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Report
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CATIONS, CHARGED PARTICLES, ELEMENTS, EVALUATION, HYDROGEN IONS, INFORMATION, IONS, MANAGEMENT, MATERIALS, METALS, MOLYBDENUM COMPOUNDS, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, RADIOACTIVE MATERIALS, RADIOACTIVE WASTE MANAGEMENT, RADIOACTIVE WASTES, REFRACTORY METAL COMPOUNDS, REFRACTORY METALS, TRANSITION ELEMENT COMPOUNDS, TRANSITION ELEMENTS, WASTE DISPOSAL, WASTE MANAGEMENT, WASTES
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