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Camilo, Ruth L.; Araujo, Izilda da C.; Mindrisz, Ana C.; Forbicini, Christina A.L.G. de O., E-mail: rcamilo@ipen.br, E-mail: icaraujo@ipen.br, E-mail: acmindri@ipen.br, E-mail: cforbici@ipen.br
Associacao Brasileira de Energia Nuclear, Rio de Janeiro, RJ (Brazil)2011
Associacao Brasileira de Energia Nuclear, Rio de Janeiro, RJ (Brazil)2011
AbstractAbstract
[en] Faced with global crisis in the production of radioisotope 99Mo, which product of decay, 99mTc, is the tracer element most often used in nuclear medicine and accounts for about 80% of all diagnostic procedures in vivo, since September 2008 Brazil is developing the project called Brazilian Multipurpose Reactor (RMB). Within the Brazilian Nuclear Program (PNB) the construction of the RMB, is seen as a long term solution to meet all domestic demand relative to the supply of radioisotopes and radiopharmaceuticals. In the process to be studied to obtain 99Mo from irradiated UA1x-A1 LEU targets employing alkaline dissolution, processing time should be minimized, considering the short half life of 99Mo and 99mTc, about 66 h and 6 h, respectively. That makes dissolution time a significant factor in the development of the process. This paper presents the results of alkaline dissolution of scraps of Al, used to simulate the dissolution process of UA1x-A1 targets. Al corresponds to about 79% of the total weight of the UA1x-A1 target. The effect of NaOH concentration on dissolution time for the interval of 1 to 3.5 mol.L-1 was studied, keeping the molar ratio in 1Al:2.16NaOH and the initial temperature of 88 degree C. The influence of reagent composition over dissolution time was studied using three different solutions: a) 3 mol.L-1 NaOH, b) 3 mol.L-1 NaOH/NaNO3 and c) 3 mol.L-1 NaOH/NaNO2, keeping the same molar ratio and temperature. The results showed that the dissolution time decreases with increasing NaOH concentration and the addition of NaNO3 or NaNO2 in the NaOH solution reduces both dissolution time and volume of gases released. (author)
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2011; 6 p; INAC 2011: International nuclear atlantic conference. Nuclear energy: new jobs for a better life; Belo Horizonte, MG (Brazil); 24-28 Oct 2011; 17. ENFIR: Meeting on nuclear reactor physics and thermal hydraulics; Belo Horizonte, MG (Brazil); 24-28 Oct 2011; 10. ENAN: Meeting on nuclear applications; Belo Horizonte, MG (Brazil); 24-28 Oct 2011; 2. ENIN: Meeting on nuclear industry; Belo Horizonte, MG (Brazil); 24-28 Oct 2011
Record Type
Miscellaneous
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Conference
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ALKALI METAL COMPOUNDS, BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, DAYS LIVING RADIOISOTOPES, DRUGS, EVEN-ODD NUCLEI, HYDROGEN COMPOUNDS, HYDROXIDES, INTERMEDIATE MASS NUCLEI, ISOTOPES, LABELLED COMPOUNDS, MANAGEMENT, MATERIALS, MEDICINE, MOLYBDENUM ISOTOPES, NUCLEAR FACILITIES, NUCLEI, OXYGEN COMPOUNDS, PROCESSING, RADIOACTIVE MATERIALS, RADIOACTIVE WASTE MANAGEMENT, RADIOISOTOPES, SODIUM COMPOUNDS, WASTE MANAGEMENT, WASTE PROCESSING
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