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Ahonen, L.; Korkeakoski, P.; Tiljander, M.; Kivikoski, H.; Laaksonen, R.
Posiva Oy, Helsinki (Finland)2008
Posiva Oy, Helsinki (Finland)2008
AbstractAbstract
[en] This report describes a quality assurance chain for the bentonite material acquisition for a nuclear waste disposal repository. Chemical, mineralogical and geotechnical methods, which may be applied in quality control of bentonite are shortly reviewed. As a case study, many of the presented control studies were performed for six different bentonite samples. Chemical analysis is a very reliable research method to control material homogeneity, because the accuracy and repeatability of the study method is extremely good. Accurate mineralogical study of bentonite is a complicated task. X-ray diffractometry is the best method to identify smectite minerals, but quantitative analysis of smectite content remains uncertain. To obtain a better quantitative analysis, development of techniques based on automatic image analysis of SEM images is proposed. General characteristics of bentonite can be obtained by rapid indicator tests, which can be done on the place of reception. These tests are methylene blue test giving information on the cation exchange capacity, swelling index and determination of water absorption. Different methods were used in the determination of cation exchange capacity (CEC) of bentonite. The results indicated differences both between methodologies and between replicate determinations for the same material and method. Additional work should be done to improve the reliability and reproducibility of the methodology. Bentonite contains water in different modes. Thus, different determination methods are used in bentonite studies and they give somewhat dissimilar results. Clay research use frequently the so-called consistency tests (liquid limit, plastic limit and plasticity index). This study method does, however, not seem to be very practical in quality control of bentonite. Therefore, only the determination of liquid limit with fall-cone method is recommended for quality control. (orig.)
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May 2008; 126 p; Also available in fulltext at http://www.posiva.fi/files/526/WR_2008-33_web.pdf o; 26 refs.; This record replaces 40102499
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Report
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ABSORPTION, BALLASTS, BENTONITE, CATIONS, CHEMICAL ANALYSIS, ICP MASS SPECTROSCOPY, IMAGES, ION EXCHANGE, MATERIALS TESTING, MINERALS, MONTMORILLONITE, PHYSICAL PROPERTIES, PLASTICITY, QUALITY ASSURANCE, QUALITY CONTROL, RADIOACTIVE WASTE DISPOSAL, RELIABILITY, SMECTITE, SWELLING, WATER, X-RAY DIFFRACTION, X-RAY FLUORESCENCE ANALYSIS
CHARGED PARTICLES, CHEMICAL ANALYSIS, CLAYS, COHERENT SCATTERING, CONTROL, DEFORMATION, DIFFRACTION, HYDROGEN COMPOUNDS, INORGANIC ION EXCHANGERS, ION EXCHANGE MATERIALS, IONS, MANAGEMENT, MASS SPECTROSCOPY, MATERIALS, MECHANICAL PROPERTIES, MINERALS, NONDESTRUCTIVE ANALYSIS, OXYGEN COMPOUNDS, RADIOACTIVE WASTE MANAGEMENT, SCATTERING, SILICATE MINERALS, SORPTION, SPECTROSCOPY, TESTING, WASTE DISPOSAL, WASTE MANAGEMENT, X-RAY EMISSION ANALYSIS
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