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Honorato, Luciana R.; Silva, Adriana A.; Soares, Bluma G.; Soares, Ketly P.
Associacao Brasileira de Polimeros (ABPol), Sao Carlos, SP (Brazil)2011
Associacao Brasileira de Polimeros (ABPol), Sao Carlos, SP (Brazil)2011
AbstractAbstract
[en] The effect of organophilic clay on the mechanical and dynamical-mechanical properties of thermoplastic elastomers based on polypropylene (PP) and nitrile rubber (NBR) was investigated. The addition of clay was performed from a master batch prepared by a solution intercalation of NBR inside the clay galleries. Since the PP/NBR blend is highly incompatible, PP functionalized with maleic anhydride (PP-g-MA) and carboxylated NBR (XNBR) were employed as compatibilizing system together with triethylene-tetramine (TETA) used as coupling agent. The addition of Clay inside the elastomeric phase of the TPV resulted in a significant decrease of the elongation at break without changes on the tensile strength. The presence of clay also promoted a slight increase of the storage modulus and the glass transition temperature. The small angle X ray scattering confirmed the high dispersion of clay inside the TPV. Analysis of light scattering small angle (SAXS) confirmed the high dispersion of clay in the matrix of the TPV. (author)
Original Title
Preparacao de termoplasticos vulcanizados dinamicamente (TPV) de NBR/PP com nanocargas de argila
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Source
2011; 6 p; 11. Brazilian congress on polymers; 11. Congresso brasileiro de polimeros; Campos do Jordao, SP (Brazil); 16-20 Oct 2011
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Miscellaneous
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Conference
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