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AbstractAbstract
[en] Selenium (Se) is naturally present in the environment. Se is essential for living organisms at trace concentrations, but it becomes rapidly toxic with their increases. The 79Se radioactive isotopes of Se, is found in nuclear wastes that may be buried in deep geological formations. In soil, Se exists in many forms and its mobility is affected by the redox potential and microbial activity. Very few studies have focused on Se behaviour at trace concentration. We have tried to distinguish the major abiotic geochemical and microbiological processes involved in the fate of trace selenite (Se(IV)) in a soil. The study was based on batch incubation in oxic or anoxic conditions of slurry suspension artificially contaminated with Se (IV) to 0.4 mg Se.kg-1 dry soil. The incubation involved sterilized and non-sterile soil samples with or without organic amendment to stimulate microbial activities. For each incubation, we followed the distribution of Se between solid, liquid and gaseous phases as well as the geochemical evolution of the solution, the composition of the atmosphere gas bottles and the soil microflora. The results showed that Se was relatively few mobile in the soil studied. Geochemical processes played a major role in controlling the Se mobility. Over time, some abiotic transformations in the solid phase contributed to increase the Se immobilisation. The microbiological processes contributed to this increase in the solid phase. Moreover, in oxic as in anoxic conditions, some microbial processes were responsible, to a lesser extent, for a dispersion of Se in the atmosphere by the production of volatile compounds. (author)
Original Title
Roles des composantes geochimiques et microbiologiques d'un sol sur le comportement du selenium en conditions oxiques et anoxiques
Primary Subject
Source
Sep 2008; 251 p; ISRN-IRSN--2008-102; 477 refs.; Available from the INIS Liaison Officer for France, see the 'INIS contacts' section of the INIS-NKM website for current contact and E-mail addresses: http://www.iaea.org/INIS/contacts/. Also available from IRSN, 31 avenue de la Division Leclerc, 92260 - Fontenay aux Roses (France); Bibliotheque de l'Universite d'Avignon et des Pays de Vaucluse, 74 rue Louis Pasteur, 84029 - Avignon cedex 1 (France); These Sciences Agronomiques
Record Type
Report
Literature Type
Thesis/Dissertation
Report Number
Country of publication
BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, DAYS LIVING RADIOISOTOPES, ELECTRON CAPTURE RADIOISOTOPES, ENVIRONMENTAL TRANSPORT, EVEN-ODD NUCLEI, INTERMEDIATE MASS NUCLEI, INTERNAL CONVERSION RADIOISOTOPES, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, MANAGEMENT, MASS TRANSFER, MINUTES LIVING RADIOISOTOPES, MOISTURE, NUCLEI, RADIOACTIVE WASTE MANAGEMENT, RADIOISOTOPES, SELENIUM ISOTOPES, STORAGE, WASTE MANAGEMENT, WASTE STORAGE, YEARS LIVING RADIOISOTOPES
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