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AbstractAbstract
[en] The ceramic films of strontium-doped lanthanum manganite (LSM) and strontium doped lanthanum manganite/Yttria-stabilized zirconia (LSM/YSZ) are used as cathodes of the high temperature solid oxide fuel cells (HTSOFC). These porous ceramic films had been deposited on the YSZ dense ceramic substrate, used as electrolyte, structural component of the module, thus conferring a configuration of half-cell called auto-support. The study of the half-cell it is basic, therefore in the interface cathode/electrolyte occurs the oxygen reduction reaction, consequently influencing in the performance of the HTSOFC. In this direction, the present work contributes for the processing of thin films, using the wet powder spraying technique, adopted for the conformation of the ceramic films for allowing the attainment of porous layers with thicknesses varied in the order of micrometers. The LSM powders were synthesized by the citrate technique and the LSM/YSZ powders synthesized by the solid mixture technique. In the stage of formation were prepared organic suspensions of LSM and LSM/YSZ fed by gravity in a manual aerograph. For the formation of the YSZ substrate was used a hydraulic uniaxial press. The attainment of solid oxide half-cells cathode/electrolyte was possible of crystalline structures hexagonal for phase LSM and cubic for phase YSZ. The half-cells micrographs show that the YSZ substrate is dense, enough to be used as solid electrolyte, and the LSM and LSM/YSZ films are presented porous with approximately 30 μm of thickness and good adherence between the cathodes and the electrolyte. The presence of composite cathode between the LSM cathode and YSZ substrate, presented an increase in the electrochemical performance in the oxygen reduction reaction. (author)
Original Title
Sintese, processamento e caracterizacao das meia-celulas de oxido solido catodo/eletrolito de manganito de lantanio dopado com estroncio/zirconia estabilizada com itria
Primary Subject
Source
2010; 123 p; Tese (Ph.D.)
Record Type
Miscellaneous
Literature Type
Thesis/Dissertation; Numerical Data
Report Number
Country of publication
ALKALINE EARTH METALS, CHALCOGENIDES, CHEMISTRY, COHERENT SCATTERING, DATA, DIFFRACTION, DIRECT ENERGY CONVERTERS, ELECTROCHEMICAL CELLS, ELECTRODES, ELECTROLYTES, ELEMENTS, FILMS, FUEL CELLS, HIGH-TEMPERATURE FUEL CELLS, INFORMATION, MATERIALS, METALS, NUMERICAL DATA, OXIDES, OXYGEN COMPOUNDS, RARE EARTHS, SCATTERING, SOLID ELECTROLYTE FUEL CELLS, TRANSITION ELEMENT COMPOUNDS, YTTRIUM COMPOUNDS, ZIRCONIUM COMPOUNDS
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