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Ritchie, I.G.; Pan, Z.-L.
Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)1992
Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)1992
AbstractAbstract
[en] The presence of hydrides is an important factor in assessing the potential for delayed hydride cracking in Zr-2.5Nb alloys, and consequently, the terminal solid solubility (TSS) of hydrogen in the material is an important parameter. In pure zirconium doped with hydrogen, the TSS is marked by a dissolution peak of internal friction on heating and a truncated precipitation peak associated with hydride nucleation on cooling. These phenomena occur only at low frequencies and are accompanied in torsion pendulum studies by autotwisting of the sample (or zero-point drift) that stops abruptly at the TSS. Neither the dissolution/precipitation peaks nor the autotwisting phenomena are observed in Zr-2.5Nb. However, the TSS is also marked by an abrupt change in the slope of Young's modulus as a function of temperature. This phenomenon is observed regardless of the frequency (in the range 1 Hz to 120 kHz) and in both pure zirconium and Zr-2.5Nb alloys. The reasons for the absence of the dissolution/precipitation peak in Zr-2.5Nb alloys are discussed and the use of Young's modulus changes to investigate the TSS of hydrogen and the hysteresis between heat-up and cool-down TSS curves is demonstrated. (author)
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Source
1992; 11 p; Also published in: M3D: Mechanics and Mechanisms of Material Damping, ASTM STP 1169, 1992, p. 385-395; 31 refs., 6 figs.
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Report
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ALLOYS, ALLOY-ZR98SN-2, CHEMICAL REACTIONS, CHROMIUM ADDITIONS, CHROMIUM ALLOYS, CORROSION RESISTANT ALLOYS, DECOMPOSITION, ELEMENTS, FRICTION, HEAT RESISTANT MATERIALS, HEAT RESISTING ALLOYS, HYDROGEN COMPOUNDS, IRON ADDITIONS, IRON ALLOYS, MATERIALS, MECHANICAL PROPERTIES, NICKEL ADDITIONS, NICKEL ALLOYS, NONMETALS, PYROLYSIS, THERMOCHEMICAL PROCESSES, TIN ALLOYS, TRANSITION ELEMENT ALLOYS, ZIRCALOY, ZIRCONIUM ALLOYS, ZIRCONIUM BASE ALLOYS
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